165905-02-2Relevant articles and documents
Metabolites of the higher fungi. Part 29. Maldoxin, maldoxone, dihydromaldoxin, isodihydromaldoxin and dechlorodihydromaldoxin. A spirocyclohexadienone, a depsidone and three diphenyl ethers: Keys in the depsidone biosynthetic pathway from a member of the
Adeboya, Monilola O.,Edwards, Raymond L.,Lassoe, Thomas,Maitland, Derek J.,Shields, Len,Whalley, Anthony J. S.
, p. 1419 - 1425 (1996)
2-(3′-Chloro-2′-hydroxy-4′-methoxy-6′- methoxycarbonylphenoxy)-6-hydroxy-4-methylbenzoic acid (dihydromaldoxin 1), 2-(3′-chloro-4′-hydroxy-2′-methoxy-6′- methoxycarbonylphenoxy)-6-hydroxy-4-methylbenzoic acid (isodihydromaldoxin 2), dechlorodihydromaldoxi
Syntheses of chloroisosulochrin and isosulochrin and biomimetic elaboration to maldoxin, maldoxone, dihydromaldoxin, and dechlorodihydromaldoxin
Yu, Min,Snider, Barry B.
, p. 4224 - 4227 (2011/10/18)
An efficient synthesis of chloroisosulochrin was accomplished using a novel ortho-selective chlorination of a phenol with sulfuryl chloride and 2,2,6,6-tetramethylpiperidine as the key step. Further elaboration by a biomimetic route converted chloroisosul