16596-07-9Relevant articles and documents
A titanium-catalyzed three-component coupling to generate α,β-unsaturated β-iminoamines
Cao, Changsheng,Shi, Yanhui,Odom, Aaron L.
, p. 2880 - 2881 (2003)
The three-component coupling of an amine, alkyne, and isonitrile is facilitated by a titanium complex bearing the N,N-di(pyrrolyl-α-methyl)-N-methylamine (dpma) ligand. From this methodology, α,β-unsaturated β-iminoamines are generated regioselectively with many substrates and are available on multigram scales. Copyright
Imminoamines and preparation thereof
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Page 9, (2010/02/07)
A process is described for producing one or more substituted iminoamines, in particular β-unsaturated β-iminoamines, in a single reaction comprising reacting one or more primary amines, alkynes, and isonitriles in the presence of a transition metal cataly