16645-01-5Relevant articles and documents
Simple Stereospecific Syntheses of (E)-1-Chloro(or Bromo)alk-1-enes from Alk-1-ynes via Hydroboration
Masuda, Yuzuru,Hoshi, Masayuki,Arase, Akira
, p. 2723 - 2726 (2007/10/02)
Stereochemically pure (E)-1-chloro(or bromo)alk-1-enes were obtained in sufficiently good yields from alk-1-ynes via hydroboration with dialkylborane followed by reactions with facile reagents; corresponding copper(II) halides, in the presence of a small
Palladium-Catalyzed Synthesis of 2,4-Dienoic Acid Derivatives from Vinylic Halides
Kim, Jin-Il,Patel, Babu A.,Heck, Richard F.
, p. 1067 - 1073 (2007/10/02)
A wide variety of vinylic bromides and iodides have been coupled with acrylic, methacrylic, crotonic, and maleic esters and in some cases with the free acids, nitriles, and amides.In general, good yields of the 2,4-dienoic acid derivatives were obtained.The stereochemistry of the products was determined and the factors influencing the stereoselec-tivity of the reaction were studied.