16668-99-8

Basic information

• Product Name: Iodonium, diphenyl-, 2,2,2-trifluoroacetate
• Synonyms: Iodonium, diphenyl-, 2,2,2-trifluoroacetate;diphenyliodonium trifluoroacetate
• CAS NO: 16668-99-8
• Molecular Weight: 394.132
• Mol File: 16668-99-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Iodonium, diphenyl-, 2,2,2-trifluoroacetate(CAS DataBase Reference)
• NIST Chemistry Reference: Iodonium, diphenyl-, 2,2,2-trifluoroacetate(16668-99-8)
• EPA Substance Registry System: Iodonium, diphenyl-, 2,2,2-trifluoroacetate(16668-99-8)

Safety Data

• Hazardous Substances Data: 16668-99-8(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 76-05-1 trifluoroacetic acid 
• 98-80-6 phenylboronic acid 
• 71-43-2 benzene 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 1483-73-4 diphenyliodonium bromide 

Downstream Products

• 126355-39-3 1-phenoxy-1H-imidazole 
• 126355-41-7 2-Ethyl-1-phenoxy-1H-imidazole 
• 122-39-4 diphenylamine 
• 4496-49-5 4-tert-butyldiphenylamine 
• 23592-67-8 N-mesitylaniline 
• 330-83-6 N-(4-fluorophenyl)aniline 
• 54446-36-5 4-bromodiphenylamine 
• 87853-73-4 3,4-dimethoxy-N-phenylaniline 
• 107456-07-5 N-(3,5-dimethoxyphenyl)-N-phenylamine 
• 836-30-6 4-ntrophenyl(phenyl)amine 
• 1205-71-6 N-(4-chlorophenyl)aniline 
• 1208-86-2 N-(4-methoxyphenyl)phenylamine 
• 605-02-7 1-phenylnaphthalene 
• 612-94-2 2-phenylnaphthalene 

Relevant articles and documents

Reaction of arenes with iodine in the presence of potassium peroxodisulfate in trifluoroacetic acid. Direct and simple synthesis of diaryliodonium triflates

Diaryliodonium triflates have been directly prepared by reaction of arenes with elemental iodine in good yields by using K2S2O 8 and TFA, followed by treatment with NaOTf. This procedure avoids the use of high temperature

Palladium-Catalyzed Four-Component Carbonylative Cyclization Reaction of Trifluoroacetimidoyl Chlorides, Propargyl Amines, and Diaryliodonium Salts: Access to Trifluoromethyl-Containing Trisubstituted Imidazoles

A palladium-catalyzed four-component carbonylative cyclization reaction for the expeditious construction of trifluoromethyl-containing trisubstituted imidazoles has been achieved. With readily accessible trifluoroacetimidoyl chlorides, propargyl amines, a

Transition-Metal-Free N-Arylation of Pyrazoles with Diaryliodonium Salts

A new synthetic method was developed for the N-arylation of pyrazoles using diaryliodonium salts. The transformation does not require any transition-metal catalyst and provides the desired N-arylpyrazoles rapidly under mild reaction condition in the presence of aqueous ammonia solution as a mild base without the use of inert atmosphere. The chemoselectivity of unsymmetric diaryliodonium salts was also explored with large number of examples.