16671-77-5

Basic information

• Product Name: Thiocyanic acid, 3-nitrophenyl ester
• CAS NO: 16671-77-5
• Molecular Formula: C7H4N2O2S
• Molecular Weight: 180.187
• Mol File: 16671-77-5.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Thiocyanic acid, 3-nitrophenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Thiocyanic acid, 3-nitrophenyl ester(16671-77-5)
• EPA Substance Registry System: Thiocyanic acid, 3-nitrophenyl ester(16671-77-5)

Safety Data

• Hazardous Substances Data: 16671-77-5(Hazardous Substances Data)

Upstream product

• 333-20-0 potassium thioacyanate 
• 540-72-7 sodium thiocyanide 
• 74863-99-3 C₃₁H₂₃N₂O₂⁽¹⁺⁾*CNS^(1-) 
• 54029-45-7 2-nitro-4-thiocyanoaniline 
• 16278-29-8 3-nitrobenzenediazonium 
• 7677-24-9 trimethylsilyl cyanide 
• 132016-29-6 methyl 3-nitrophenyl sulfoxide 
• 537-91-7 bis(3-nitrophenyl) disulfide 
• 13331-27-6 m-nitrobenzene boronic acid 
• 75-52-5 nitromethane 
• 99-09-2 3-nitro-aniline 
• 586-36-7 3-nitrophenyldiazonium tetrafluoroborate 
• 78-67-1 2,2'-azobis(isobutyronitrile) 
• 54029-46-8 acetic acid-(2-nitro-4-thiocyanato-anilide) 

Downstream Products

• 70415-89-3 1-nitro-3-(propan-2-ylsulfanyl)benzene 
• 24933-39-9 (difluoromethyl)(3-nitrophenyl)thioether 
• 2976-31-0 1-(ethylsulfonyl)-3-nitrobenzene 
• 80213-20-3 1-nitro-3-(propane-2-sulfonyl)benzene 
• 24906-87-4 <3-Amino-phenyl>-difluormethyl-sulfoxid 
• 24933-59-3 3-Difluormethylmercapto-anilin 
• 24933-66-2 1-((difluoromethyl)sulfinyl)-3-nitrobenzene 
• 369-68-6 3-(trifluoromethylthio)aniline 
• 90109-81-2 (3-nitro-phenyl)-trichloromethyl sulfide 
• 370-47-8 (3-nitrophenyl)(trifluoromethyl)sulfane 
• 13118-31-5 dimethyl-(3-nitro-phenyl)-sulfonium ; methyl sulfate 
• 107518-44-5 (3-methylsulfanyl-phenyl)-phenyl-diazene 
• 857586-50-6 bis-(3-methylsulfanyl-phenyl)-diazene-N-oxide 
• 3996-40-5 (3-nitro-phenylsulfanyl)-acetic acid 

Relevant articles and documents

Nitromethane as a cyanating reagent for the synthesis of thiocyanates

Nitromethane has been developed to be an effective cyanating reagent for the synthesis of thiocyanates. In the presence of iodine and base, a wide range of disulfides were reacted with nitromethane smoothly to give diverse thiocyanates in moderate to good yields.

Selectfluor-initiated cyanation of disulfides to thiocyanates

A Selectfluor-initiated cyanation of disulfides to thiocyanates has been developed. In this process, Selectfluor was employed as the oxidant and trimethylsilyl cyanide was used as the cyanation reagent. It provides an eco-friendly and simple way to synthesize the thiocyanates.

Transition-metal-free synthesis of thiocyanato- or nitro-arenes through diaryliodonium salts

A transition-metal-free approach to facile synthesis of thiocyanato- and nitro-arenes was developed from KSCN (potassiumthiocyanate) or NaNO2with diaryliodonium salts in good yields under mild conditions. The reaction was compatible with a variety of sensitive functional substituents such as halides and nitro and ester groups. The usefulness of arylation products has been realized. (Formula Present).