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166942-24-1

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166942-24-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 166942-24-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,6,9,4 and 2 respectively; the second part has 2 digits, 2 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 166942-24:
(8*1)+(7*6)+(6*6)+(5*9)+(4*4)+(3*2)+(2*2)+(1*4)=161
161 % 10 = 1
So 166942-24-1 is a valid CAS Registry Number.

166942-24-1Downstream Products

166942-24-1Relevant articles and documents

New silane reduction of aromatic ketones mediated by titanium tetrachloride : A synthesis of γ- and δ-aryl substituted amino acids

Yato, Michihisa,Homma, Koichi,Ishida, Akihiko

, p. 233 - 254 (2007/10/03)

Several N-protected 4-aryl-2-aminobutanoic acids (γ-aryl substituted amino acids ; 7a-f) and N-protected 5-aryl-2-aminopentanoic acids (δ-aryl substituted amino acids ; 8a,b and d) were prepared in good yields by reduction of the corresponding aromatic or heteroaromatic ketones (3 and 4) with triethylsilane (Et3SiH) or dimethylphenylsilane (PhMe2SiH) in the presence of titanium tetrachloride (TiCl4), respectively. The reduction proceeded without racemization and was successfully applied to the synthesis of optically active γ-and δ-aryl substituted amino acids (14a and 15a).

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