167074-40-0

Basic information

• Product Name: phenyl 3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-1-seleno-α-D-galactopyranoside
• Synonyms: phenyl 3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-1-seleno-α-D-galactopyranoside
• CAS NO: 167074-40-0
• Molecular Weight: 432.338
• Mol File: 167074-40-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: phenyl 3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-1-seleno-α-D-galactopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-1-seleno-α-D-galactopyranoside(167074-40-0)
• EPA Substance Registry System: phenyl 3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-1-seleno-α-D-galactopyranoside(167074-40-0)

Safety Data

• Hazardous Substances Data: 167074-40-0(Hazardous Substances Data)

Upstream product

• 4098-06-0 triacetyl-D-galactal 
• 150809-76-0 phenyl 3,4,6-tri-O-acetyl-2-azido-2-deoxy-1-seleno-α-D-galactopyranoside 
• 1666-13-3 diphenyl diselenide 
• 100-52-7 benzaldehyde 
• 862851-12-5 phenyl 2-azido-2-deoxy-1-seleno-α-D-galactopyranoside 

Downstream Products

• 167074-41-1 phenyl 3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-1-seleno-α-D-galactopyranoside 
• 1263481-24-8 allyl 2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranoside 
• 122796-27-4 allyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside 
• 1358951-16-2 allyl (3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside 
• 1358951-17-3 allyl (3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranosyl)-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside 
• 1358951-18-4 allyl (2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside 
• 1358951-26-4 allyl (3,4,6-tri-O-acetyl-2-O-methoxycarbonyl-β-D-galactopyranosyl)-(1->3)-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside 
• 1358951-27-5 allyl (3,4,6-tri-O-acetyl-2-O-methoxycarbonyl-β-D-galactopyranosyl)-(1->3)-(2-acetamido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside 
• 138688-75-2 3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactose 
• 138688-74-1 3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactose 
• 132183-16-5 tert-butyldiphenylsilyl O-2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside 

Relevant articles and documents

A concise synthesis of the O-glycosylated amino acid building block; using phenyl selenoglycoside as a glycosyl donor

A new glycosylation methodology for synthesizing a protected TF antigen is described. The key step is to use phenyl selenoglycoside as a glycosyl donor, thereby successfully establishing O-linked Fmoc-protected threoninyl monosaccharide in an excellent yi

Stripping off water at ambient temperature: Direct atom-efficient acetal formation between aldehydes and diols catalyzed by water-tolerant and recoverable vanadyl triflate

(Chemical Equation Presented) Aromatic aldehydes can be readily protected as acetals with 1,2- and 1,3-diols by using vanadyl triflate as a catalyst in CH3CN at ambient temperature. Carbohydrate-based 1,2- and 1,3-diols can similarly be protected in good to excellent yields. The catalyst can be readily recovered from the aqueous layer. In combination with vanadyl triflate-catalyzed sequential regioselective, reductive acetal opening and chemoselective acylations, the title method allows for differential functionalization of all four hydroxyl units in a given glucopyranoside.