16732-86-8Relevant articles and documents
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Turner et al.
, p. 4116,4119 (1957)
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Ichinohe et al.
, p. 3614 (1969)
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Eck,Van Peursem,Hollingsworth
, p. 171,173 (1939)
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REDUCTIVE REMOVAL OF ALLYLIC FUNCTIONAL GROUPS BY NICKEL BORIDE
Sarma, D. N.,Sharma, R. P.
, p. 2581 - 2584 (1985)
Reductive removal of an allylic functional group proceeds most easily and efficiently with nickel boride as the bond being cleaved becomes a better leaving group ( e.g.OCH3OHOSiMe3OCOCH3OCOCF3 )
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Wall,E.N.,McKenna,J.
, p. 318 - 320 (1970)
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Mauthner
, p. 1113,1117 (1907)
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Dephosphorylation of Cyano Diethyl Phosphates by Reduction with Lithium-Liquid Ammonia: An Efficient Method for Conversion of Carbonyl Compounds into Nitriles
Yoneda, Ryuji,Osaki, Takahiro,Harusawa, Shinya,Kurihara, Takushi
, p. 607 - 610 (2007/10/02)
Cyano diethyl phosphate derivatives of aromatic carbonyl compounds and α,β-unsaturated ketones were successively dephosphorylated by reduction with lithium in liquid ammonia followed by treatment with isoprene or alkyl halides to give β,γ-unsaturated nitriles or α-alkyl-β,γ-unsaturated nitriles in moderate to good yields.
Acid-catalysed Rearrangements of Steroid Alkenes. Part 2. A Re-investigation of the Backbone Rearrangement of Cholest-5-ene
Peakman, Torren M.,Ellis, Karen,Maxwell, James R.
, p. 1071 - 1076 (2007/10/02)
Backbone rearrangement of cholest-5-ene (1) with boron trifluoride-diethyl ether gives, in addition to the well known diacholest-13(17)-enes (4a,b), their 10β counterparts (6a,b) as minor products.With anhydrous toluene-p-sulphonic acid-acetic acid, additional products include components also isomeric at C-10 and C-20 and having a spiro C/D ring junction.A proposed scheme for the rearrangement is given.
