16737-71-6

Basic information

• Product Name: Ethanol, 2-(2,6-dimethylphenoxy)-
• CAS NO: 16737-71-6
• Molecular Formula: C10H14O2
• Molecular Weight: 166.22
• Mol File: 16737-71-6.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Ethanol, 2-(2,6-dimethylphenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanol, 2-(2,6-dimethylphenoxy)-(16737-71-6)
• EPA Substance Registry System: Ethanol, 2-(2,6-dimethylphenoxy)-(16737-71-6)

Safety Data

• Hazardous Substances Data: 16737-71-6(Hazardous Substances Data)

Upstream product

• 576-26-1 2.6-dimethylphenol 
• 540-51-2 2-bromoethanol 
• 576-22-7 2-Bromo-m-xylene 
• 107-21-1 ethylene glycol 
• 107-07-3 2-chloro-ethanol 
• 75-21-8 oxirane 
• 96-49-1 [1,3]-dioxolan-2-one 
• 6279-47-6 ethyl 2-(2,6-dimethylphenoxy)acetate 
• 445283-38-5 2-[2-(2,6-dimethyl-phenoxy)-ethoxy]-tetrahydro-pyran 

Downstream Products

• 72102-89-7 2,6-dimethylphenoxyacetaldehyde 
• 38285-13-1 2-(2-chloroethyl)-1,3-dimethylbenzene 
• 1347727-76-7 trans-(±)-4N-[(2,6-dimethylphenoxy)ethyl]aminocyclohexan-1-ol 
• 39085-53-5 Essigsaeure-<2-(2,6-dimethyl-phenoxy)-ethylester> 
• 116773-67-2 [2-(2,6-dimethyl-phenoxy)-ethyl]-4-toluenesulfonate 
• 227750-60-9 (2,6-dimethyl)-phenoxyethyl-4-toluenesulfonate 
• 37136-92-8 2-(2,6-Dimethyl-phenoxy)-1-bromo-ethane 

Relevant articles and documents

A photopolymerization initiator, and ink composition using the same

PROBLEM TO BE SOLVED: To provide a compound useful as a water soluble photopolymerization initiator, and an ink composition containing the same.SOLUTION: A compound is represented by general formula (1) [in general formula (1), each of Rto Rindependently represents a hydrogen atom or a substituent, however, at least one of Rto Ris a group represented by R-X-* (wherein Xrepresents an oxygen atom or a sulfur atom, Rrepresents a substituent, and * represents a site connecting with a benzene ring), also Rrepresents a substituent other than an aryl group and a heterocyclic group, and two or more Rs may be identical to or different from one another].

Zirconium complexes with pendant aryloxy groups attached to the metallocene moiety by ethyl or hexyl spacers

Four zirconium complexes with pendant aryloxy groups attached to the metallocene moiety by ethyl or hexyl spacers have been synthesized and characterized by spectroscopic methods and HR-MS or elemental analysis. The solid state structure of bis[{6-(2,6-dimethylphenoxy)hexyl}cyclopentadienyl] zirconium dichloride was determined by single crystal X-ray diffraction. The prepared complexes were tested as catalyst precursors in the polymerization of ethylene upon activation with MAO. The results showed a marked effect of the spacer length on the catalytic activity, while only a minor effect of the substitution on the aryl group, which affected its steric properties.

β-Hydroxyalkylation of sterically hindered phenols with epoxides in acid medium

Reactions of 2,6-dialkylphenols with ethylene oxide, propylene oxide and epichlorohydrin in the presence of SnCl4 at the temperature from -5 to +5°C leads to the formation of respective phenols containing a hydroxy group in the β-position of the aliphatic chain of the para-substituent. The conditions for maximum selectivity of the reaction of 2,6-di-tert-butylphenol with ethylene oxide were determined. By HPLC-MS method the directions of the side reactions were explored. The method has been successfully tested in a pilot installation. With 2,6-dimethylphenol instead of 2,6-di-tert-butylphenol a sharp increase occurs in the content of ethers in the reaction product. With epichlorohydrin, 2,6-di-tert-butylphenol affords a product, which is easily converted into an epoxide containing a sterically hindered phenol in its structure.