167385-31-1Relevant articles and documents
Prop-2-ynyl Alcohol as a Precursor to the η1-Ethenyl Ligand
O'Connor, Joseph M.,Hiibner, Kristin
, p. 1209 - 1210 (1995)
In the presence of water the unsaturated iridium(III) metallacyclopentadiene halide complex cyclo(PPh3)2Cl (1, R = CO2Me) undergoes reaction with prop-2-ynyl alcohol, or methyl prop-2-ynyl ether at room temperature to give the η1-ethenyl complex cyclo(PPh3)2(CO)(η1-CH=CH2) (3, R = CO2Me) in quantitative yield.