167482-50-0

Basic information

• Product Name: 1,2-O-Isopropylidene-3-O-(p-phenylbenzyl)-4,5-O-<(1'R)-3'-methyl-2'-buten-1'-yl>-β-D-fructopyranose
• Synonyms: 1,2-O-Isopropylidene-3-O-(p-phenylbenzyl)-4,5-O-<(1'R)-3'-methyl-2'-buten-1'-yl>-β-D-fructopyranose
• CAS NO: 167482-50-0
• Molecular Weight: 452.547
• Mol File: 167482-50-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2-O-Isopropylidene-3-O-(p-phenylbenzyl)-4,5-O-<(1'R)-3'-methyl-2'-buten-1'-yl>-β-D-fructopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-O-Isopropylidene-3-O-(p-phenylbenzyl)-4,5-O-<(1'R)-3'-methyl-2'-buten-1'-yl>-β-D-fructopyranose(167482-50-0)
• EPA Substance Registry System: 1,2-O-Isopropylidene-3-O-(p-phenylbenzyl)-4,5-O-<(1'R)-3'-methyl-2'-buten-1'-yl>-β-D-fructopyranose(167482-50-0)

Safety Data

• Hazardous Substances Data: 167482-50-0(Hazardous Substances Data)

Upstream product

• 6347-01-9 fructopyranose 
• 25018-67-1 1,2;4,5-di-O-isopropylidene-β-D-(-)-fructopyranose 
• 1740-74-5 1,1-diethoxy-3-methyl-2-butene 
• 167482-35-1 1,2-O-Isopropylidene-3-O-(p-phenylbenzyl)-β-D-fructopyranose 

Downstream Products

• 28624-52-4 (R)-2,2-dimethylcyclopropanecarboxylic acid 
• 14590-53-5 (+)-1S-2,2-dimethylcyclopropane-carboxylic acid 

Relevant articles and documents

Asymmetric Cyclopropanation Using New Chiral Auxiliaries Derived from D-Fructose

Acetals of α,β-unsaturated aldehydes with 3-O-alkylated derivatives of 1,2-O-isopropylidene-β-D-fructopyranose and 1,2-O-isopropylidene-β-D-psicopyranose, which are readily available from D-fructose, were cyclopropanated with Et2Zn and CH2I2 with good diastereoselectivity.The effects of structure of the acetals on enantioselectivity were examined.