167971-38-2Relevant articles and documents
Substituted Tetraethynylethylene–Tetravinylethylene Hybrids
Connor, Kieran P. E.,Horvath, Kelsey L.,Magann, Nicholas L.,Sherburn, Michael S.,Sowden, Madison J.,Westley, Erin
supporting information, p. 977 - 986 (2022/02/03)
A general synthetic approach to molecular structures that are hybrids of tetraethynylethylene (TEE) and tetravinylethylene (TVE) is reported. The synthesis permits the controlled preparation of many previously inaccessible structures, including examples w
Regio- and chemoselective coupling of polyalkynes: A convenient access to polyarylacetylenes and polyenynes
Halbes-Letinois, Ulla,Vasiliev, Aleksander,Pale, Patrick
, p. 2828 - 2834 (2007/10/03)
Mono- or disilylated α,ω-diynes and disilylated triynes can be regioselectively homologated at each acetylenic end, silylated or not, by two and three, respectively, successive Pd/ Ag-catalyzed coupling reactions. Each coupling being selective either for
2. Tetraethynylethenes: Fully Cross-Conjugated ?-Electron Chromophores and Molecular Scaffolds for All-Carbon Networks and Carbon-Rich Nanomaterials
Anthony, John,Boldi Armen M.,Rubin, Ives,Hobi, Markus,Gramlich, Volker,et al.
, p. 13 - 45 (2007/10/02)
The preparation of tetraethynylethene (3,4-diethynylhex-3-ene-1,5-diyne) 1 as well as of a great diversity of differentially mono-, di-, and triprotected derivatives by newly developed synthetic routes is described.These fully cross-conjugated molecules a