168105-48-4

Basic information

• Product Name: C₇₂H₇₀O₁₀
• CAS NO: 168105-48-4
• Molecular Weight: 1095.34
• Mol File: 168105-48-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₇₂H₇₀O₁₀(CAS DataBase Reference)
• NIST Chemistry Reference: C₇₂H₇₀O₁₀(168105-48-4)
• EPA Substance Registry System: C₇₂H₇₀O₁₀(168105-48-4)

Safety Data

• Hazardous Substances Data: 168105-48-4(Hazardous Substances Data)

Upstream product

• 6207-45-0 2-(allyloxy)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)-tetrahydro-2H-pyran 
• 141196-28-3 trimethyl(((2S,3S,4R,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)-tetrahydro-2H-pyran-2-yl)ethynyl)silane 
• 98991-08-3 2-iodo-1-methoxy-3-nitrobenzene 
• 168253-07-4 (2R,3R,4R,5S,6S)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-6-ethynyl-tetrahydro-pyran 
• 197243-48-4 2-iodo-3-nitrophenol 
• 603-85-0 2-Amino-3-nitrophenol 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 168336-52-5 C₃₉H₄₄O₆Si 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 

Relevant articles and documents

Total synthesis of indole-3-acetonitrile-4-methoxy-2-C-β-d- glucopyranoside. Proposal for structural revision of the natural product

Indole-3-acetonitrile-4-methoxy-2-C-β-d-glucopyranoside (1), a novel C-glycoside from Isatis indigotica with important cytotoxic activity, has been prepared in ten steps from ethynyl-β-C-glycoside 3 and 2-iodo-3-nitrophenyl acetate 6. Key steps in the synthesis include a Sonogashira coupling and a CuI-mediated indole formation. NMR spectroscopic data for synthetic 1 differs from that reported for the natural product. A revised structure for the natural product, containing an alternate carbohydrate substituent, is proposed. The Royal Society of Chemistry 2012.