16814-45-2

Basic information

• Product Name: 1-tosyl-1,2,3,4-tetrahydronaphthalene
• Synonyms: 1-tosyl-1,2,3,4-tetrahydronaphthalene
• CAS NO: 16814-45-2
• Molecular Weight: 286.395
• Mol File: 16814-45-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-tosyl-1,2,3,4-tetrahydronaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-tosyl-1,2,3,4-tetrahydronaphthalene(16814-45-2)
• EPA Substance Registry System: 1-tosyl-1,2,3,4-tetrahydronaphthalene(16814-45-2)

Safety Data

• Hazardous Substances Data: 16814-45-2(Hazardous Substances Data)

Upstream product

• 529-33-9 1,2,3,4-Tetrahydro-1-naphthol 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 98-59-9 p-toluenesulfonyl chloride 
• 119-64-2 tetralin 
• 17360-25-7 N-tosylvaline 
• 38622-91-2 [(p-methylphenyl)sulfonylmethyl]isonitrile 

Relevant articles and documents

Visible-Light-Catalyzed in Situ Denitrogenative Sulfonylation of Sulfonylhydrazones

A photocatalyzed in situ denitrogenative sulfonylation of N-arylsulfonyl hydrazones has been developed. This transformation provides a low-carbon strategy to assemble arylalkyl sulfones in a stepwise denitrogenation/sulfonylation manner.

Substrate- and temperature-controlled divergence in reactions of alcohols with TosMIC catalyzed by BF3 · Et2O: Facile access to sulfinates and sulfones

An efficient BF3 · Et2O-catalyzed divergent synthesis of sulfinate esters and sulfones through C–O and C–S bond formation has been achieved from alcohols and p-toluenesulfonylmethyl isocyanide (TosMIC). Various alcohols reacted smoothly with TosMIC under the present conditions at room temperature providing sulfinate esters exclusively. By tuning the reaction temperature, the alcohols that provide highly stabilized carbocation in the reaction medium afforded sulfones as sole products. This study was aimed at understanding the regioselectivity of ambidentate sulfinate ion and to elucidate the interpretation of sulfinate/sulfone scaffolds.