16825-79-9

Basic information

• Product Name: Benzene, 1-iodyl-4-nitro-
• CAS NO: 16825-79-9
• Molecular Formula: C6H4INO4
• Molecular Weight: 281.007
• Mol File: 16825-79-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-iodyl-4-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-iodyl-4-nitro-(16825-79-9)
• EPA Substance Registry System: Benzene, 1-iodyl-4-nitro-(16825-79-9)

Safety Data

• Hazardous Substances Data: 16825-79-9(Hazardous Substances Data)

Upstream product

• 636-98-6 p-nitrobenzene iodide 
• 64846-47-5 4-nitrobenzene 
• 827-98-5 dichloro(4-nitrophenyl)-λ³-iodane 

Downstream Products

• 636-98-6 p-nitrobenzene iodide 
• 62-23-7 4-nitro-benzoic acid 
• 1516-60-5 4-nitrophenyl azide 
• 98-95-3 nitrobenzene 
• 16447-86-2 4-<18F>-fluoronitrobenzene 
• 305-85-1 2,6-diiodo-4-nitrophenol 
• 100-25-4 para-dinitrobenzene 
• 66959-12-4 p-Bis-(trifluoracetoxy)-iodylnitrobenzol 
• 64846-45-3 p-Bis-(acetoxy)-iodylnitrobenzol 
• 64846-44-2 C₂₂H₄F₂₈INO₁₀ 
• 64846-41-9 C₁₄H₄F₁₂INO₁₀ 

Relevant articles and documents

Mild and efficient synthesis of iodylarenes using Oxone as oxidant

Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

Syntheses of (diacetoxyiodo)arenes or iodylarenes from iodoarenes, with sodium periodate as the oxidant

Easy, safe, and effective novel methods for preparing either (diacetoxyiodo)-(arenes, ArI(OAc)2, or iodylarenes, ArIO2, from the corresponding iodoarenes, ArI, using sodium periodate as the oxidant are presented in this paper. In order to obtain 2- and 4-iodylbenzoic acids, the respective sodium salts of 2- and 4-iodobenzoic acids should be used as the starting substrates, because mixtures containing the corresponding iodosyl derivatives as the main products along with the intended iodyl compounds are produced from the free parent acids.

173.Ru-Catalyzed Oxidations with Iodosylbenzene Derivatives. Substituent Effects on Selectivity in Oxidation of Sulfides and Alcohols

Oxidation of sulfides witth PhIO/RuCl2(PPh3) leads to sulfones.Electronwithdrawing substituents in the aromatic ring of PhIO reduce the reactivity and improves selectivity of the system.Thus, with m-iodosylbenzoic acid sulfides are converted to sulfoxide.Under the same conditions aliphatic primary alcohols are transformed to aldehydes with m-iodosylbenzoic acid, while PhIO affords carboxylic acids.