1684-07-7Relevant articles and documents
Effect of Cp-Ligand Methylation on Rhodium(III)-Catalyzed Annulations of Aromatic Carboxylic Acids with Alkynes: Synthesis of Isocoumarins and PAHs for Organic Light-Emitting Devices
Molotkov, Alexander P.,Arsenov, Mikhail A.,Kapustin, Daniil A.,Muratov, Dmitry V.,Shepel', Nikolay E.,Fedorov, Yury V.,Smol'yakov, Alexander F.,Knyazeva, Elena I.,Lypenko, Dmitry A.,Dmitriev, Artem V.,Aleksandrov, Alexey E.,Maltsev, Eugeny I.,Loginov, Dmitry A.
, p. 334 - 345 (2020)
An efficient protocol was developed for the synthesis of π-extended isocoumarins and polycyclic aromatic hydrocarbons based on the oxidative coupling of aromatic carboxylic acids with internal alkynes catalyzed by (cyclopentadienyl)rhodium complexes. The
Cp*IrIII-catalyzed oxidative coupling of benzoic acids with alkynes
Frasco, Daniel A.,Lilly, Cassandra P.,Boyle, Paul D.,Ison, Elon A.
, p. 2421 - 2429 (2013)
Cp*Ir(III) complexes have been shown to catalyze the oxidative coupling of benzoic acids with alkynes in methanol at 60 C to form a variety of isocoumarins. The use of AgOAc as an oxidant was required to facilitate significant product formation. Alkyl alkynes were shown to be more reactive substrates than aryl alkynes, and a number of functional groups were tolerated on benzoic acid. Combined mechanistic and computational studies (BP86) revealed that (1) C-H activation occurs via an acetate-assisted mechanism; (2) C-H activation is not turnover limiting; and (3) the oxidant oxidizes the reduced form of the catalyst via an Ir(I)-Ir(II)-Ir(III) sequence.
Cationic iridacarboranes [3-(arene)-3,1,2-IrC2B9H11]+ and [3-(MeCN)3-3,1,2-IrC2B9H11]+: Synthesis, reactivity, and bonding. Catalysis of oxidative coupling
Loginov, Dmitry A.,Belova, Alena O.,Vologzhanina, Anna V.,Kudinov, Alexander R.
, p. 232 - 240 (2015)
(Arene)iridacarboranes [3-(arene)-3,1,2-IrC2B9H11]+ (arene = benzene (1a), toluene (1b), o-xylene (1c), m-xylene (1d), durene (1e)) were synthesized by reaction of [(cod)IrCl]2 with Tl[Tl(η-7,8-C
Computational Characterization of the Mechanism for the Oxidative Coupling of Benzoic Acid and Alkynes by Rhodium/Copper and Rhodium/Silver Systems
Funes-Ardoiz, Ignacio,Maseras, Feliu
, p. 12383 - 12388 (2018)
DFT calculations were applied to study the oxidative coupling between benzoic acid and 1-phenyl-1-propyne catalyzed by [CpRhCl2]2 (Cp=cyclopentadienyl) by using either Cu(OAc)2(H2O) or Ag(OAc) as the terminal ox
Rhodacarboranes as catalysts for oxidative coupling of benzoic acid with diphenylacetylene
Loginov,Belova,Kudinov
, p. 983 - 986 (2014)
Rhodacarboranes [(9-SMe2-7,8-Me2-C2B9H8)RhCl2]2, [(1-ButNH-1,7,9-C3B8H10)-RhI2]2, [(9-SMe2-7,8-C
Easy Access to Versatile Catalytic Systems for C?H Activation and Reductive Amination Based on Tetrahydrofluorenyl Rhodium(III) Complexes
Kharitonov, Vladimir B.,Runikhina, Sofiya A.,Nelyubina, Yulia V.,Muratov, Dmitry V.,Chusov, Denis,Loginov, Dmitry A.
supporting information, p. 10903 - 10912 (2021/06/28)
On the basis of the 1,2,3,4-tetrahydrofluorenyl ligand, a simple approach was developed to new effective rhodium catalysts for the construction of C?C and C?N bonds. The halide compounds [(η5-tetrahydrofluorenyl)RhX2]2 (2
Synthesis of Benzo-Fused Cyclic Compounds via Rhodium-Catalyzed Decarboxylative Coupling of Aromatic Carboxylic Acids with Alkynes
Inai, Yasuhito,Usuki, Yoshinosuke,Satoh, Tetsuya
supporting information, p. 3029 - 3036 (2021/04/15)
The decarboxylative coupling of diversely substituted benzoic acids with internal alkynes proceeds smoothly in the presence of a [RhCl(cod)] 2/1,2,3,4-tetraphenyl-1,3-cyclopentadiene catalyst system to selectively produce highly substituted nap
