16888-99-6

Basic information

• Product Name: Benzamide, N-[2-(benzoyloxy)-1,1-dimethylethyl]-
• CAS NO: 16888-99-6
• Molecular Formula: C18H19NO3
• Molecular Weight: 297.354
• Mol File: 16888-99-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzamide, N-[2-(benzoyloxy)-1,1-dimethylethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N-[2-(benzoyloxy)-1,1-dimethylethyl]-(16888-99-6)
• EPA Substance Registry System: Benzamide, N-[2-(benzoyloxy)-1,1-dimethylethyl]-(16888-99-6)

Safety Data

• Hazardous Substances Data: 16888-99-6(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 201230-82-2 carbon monoxide 
• 124-68-5 2-Amino-2-methyl-1-propanol 
• 98-88-4 benzoyl chloride 

Relevant articles and documents

Synthesis, crystal structures and catalytic activities of new palladium(II)–bis(oxazoline) complexes

Palladium–bis(oxazoline) complexes (Pd-BOX-A and Pd-BOX-B) were synthesized and characterized by 1H, 13C NMR, IR and elemental analysis. The molecular structures of the complexes were confirmed by single-crystal X-ray analysis. In both cases, the palladium center is coordinated by the nitrogen atoms of the two oxazoline rings and two chloride ligands in a distorted square planar geometry. Despite the fact that the bis(oxazoline) ligand is achiral, the asymmetrical substitution on the phenyl spacer and the rigid backbone of the complex Pd-BOX-A induce inherent chirality and the compound crystallizes as a racemic mixture. Both complexes were found to be highly effective catalysts for Suzuki–Miyaura, Mizoroki–Heck and Sonogashira cross-coupling reactions. They also show excellent catalytic activities toward carbonylative coupling reactions.