16894-69-2Relevant articles and documents
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Willard,Perkins,Blicke
, p. 737 (1948)
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Phenylation of Organic Derivatives of Mercury, Silicon, Tin, and Bismuth with Pentaphenylantimony and Pentaphenylphosphorus
Sharutin,Sharutina,Senchurin,Egorova,Ivanenko,Petrov
, p. 202 - 203 (2007/10/03)
Pentaphenylantimony and -phosphorus react with arylmercury chlorides in toluene at room temperature to give diaryl derivatives of mercury in yields of up to 95%. The reactions of pentaphenylantimony and -phosphorus with silicon and tin halides involve ary
Catalytic C-phenylation of methyl acrylate with tetraphenylantimony(v) halides and carboxylates
Gushchin,Grunova,Moiseev,Morozov,Shavyrin,Dodonov
, p. 1376 - 1379 (2007/10/03)
Catalytic C-phenylation of methyl acrylate to methyl cinnamate with the Ph4SbX complexes (X = F, Cl, Br, OH, OAc, O2CEt) in the presence of the palladium compounds PdCl2, Pd(OAc)2, Pd2(dba)3, Pd(Ph3P)2Cl2, and Pd(dppf)Cl2 (dba is dibenzylideneacetone and dppf is bis(diphenylphosphinoferrocene)) was studied in organic solvents (MeCN, THF, DMF, MeOH, and AcOH). The highest yield of methyl cinnamate (73% based on the starting organometallic compound) was obtained for the Ph4SbCl- PdCl2 (1:0.04) system in acetonitrile.