16954-38-4Relevant articles and documents
Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step
Gong, Yuanzheng,Yang, Chun,Ji, Hongwei,Chen, Chuncheng,Ma, Wanhong,Zhao, Jincai
supporting information, p. 2048 - 2051 (2017/08/23)
In aqueous TiO2 photocatalytic hydroxylation of weakly polar aromatics, a series of inverse H/D KIEs of 0.7–0.8 were observed, which is different than the normal H/D kinetic isotope effects (KIEs) usually observed for polar aromatics. This result indicated that the oxidation started by photo-induced hvb + can be the rate-determining step.
H/D exchange at aromatic and heteroaromatic hydrocarbons using D 2O as the deuterium source and ruthenium dihydrogen complexes as the catalyst
Prechtl, Martin H. G.,Hoelscher, Markus,Ben-David, Yehoshoa,Theyssen, Nils,Loschen, Rebekka,Milstein, David,Leitner, Walter
, p. 2269 - 2272 (2008/02/14)
Getting heavy: At temperatures as low as 50°C, D2O can serve as a cheap and readily available deuterium source for the efficient deuteration of aromatic and heteroaromatic substrates if nonclassical ruthenium hydride complexes are used as catalysts (see scheme). DFT calculations support a catalytic cycle comprising σ-bond metathesis as the key step for the exchange processes. (Chemical Equation Presented).
DEUTERIUM ISOTOPE EFFECTS IN THE META PHOTOCYCLOADDITION OF AROMATIC COMPOUNDS TO ALKENES
de Vaal, P.,Lodder, G.,Cornelisse, J.
, p. 4395 - 4398 (2007/10/02)
Secondary deuterium isotope effects were observed in the meta photocycloaddition of several aromatic compounds to cyclopentene.
