169612-46-8

Basic information

• Product Name: Methyl N-(N-benzyloxycarbonyl-L-alanyl)-O-tert-butyldimethylsilyl-L-serinate
• Synonyms: Methyl N-(N-benzyloxycarbonyl-L-alanyl)-O-tert-butyldimethylsilyl-L-serinate
• CAS NO: 169612-46-8
• Molecular Weight: 438.596
• Mol File: 169612-46-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Methyl N-(N-benzyloxycarbonyl-L-alanyl)-O-tert-butyldimethylsilyl-L-serinate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl N-(N-benzyloxycarbonyl-L-alanyl)-O-tert-butyldimethylsilyl-L-serinate(169612-46-8)
• EPA Substance Registry System: Methyl N-(N-benzyloxycarbonyl-L-alanyl)-O-tert-butyldimethylsilyl-L-serinate(169612-46-8)

Safety Data

• Hazardous Substances Data: 169612-46-8(Hazardous Substances Data)

Upstream product

• 19542-34-8 N-(benzyloxycarbonyl)-L-alanyl-L-serine methyl ester 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Relevant articles and documents

Mild, Redox-Neutral Formylation of Aryl Chlorides through the Photocatalytic Generation of Chlorine Radicals

We report a redox-neutral formylation of aryl chlorides that proceeds through selective 2-functionalization of 1,3-dioxolane through nickel and photoredox catalysis. This scalable benchtop approach provides a distinct advantage over traditional reductive carbonylation in that no carbon monoxide, pressurized gas, or stoichiometric reductant is employed. The mild conditions give unprecedented scope from abundant and complex aryl chloride starting materials.

Methylene piperazine-2,5-diones as templates for the synthesis of amino acid derivatives

Methylene piperazine-2,5-diones 5a and 5b are important synthetic intermediates. The preparation as well as the use of these compounds in the synthesis of amino acid derivatives are described. Our studies demonstrate that excellent chiral induction in car