16974-34-8

Basic information

• Product Name: dodec-9-en-1-yl acetate
• Synonyms: 9-dodecen-1-ol, acetate; Dodec-9-en-1-yl acetate
• CAS NO: 16974-34-8
• Molecular Formula: C₁₄H₂₆O₂
• Molecular Weight: 226.355
• Mol File: 16974-34-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 300.1°C at 760 mmHg
• Flash Point: 96.5°C
• Density: 0.881g/cm³
• Vapor Pressure: 0.00114mmHg at 25°C
• Refractive Index: 1.448
• CAS DataBase Reference: dodec-9-en-1-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: dodec-9-en-1-yl acetate(16974-34-8)
• EPA Substance Registry System: dodec-9-en-1-yl acetate(16974-34-8)

Safety Data

• Hazardous Substances Data: 16974-34-8(Hazardous Substances Data)

Upstream product

• 592-47-2 3-hexene 
• 50816-18-7 9-decen-1-yl acetate 
• 71566-57-9 (E)-2-(9-Dodecenyloxy)tetrahydropyrane 
• 75-36-5 acetyl chloride 
• 1576-96-1 (E)-2-penten-1-ol 
• 7348-71-2 (E)-1-bromo-2-pentene 
• 13019-22-2 9-Decen-1-ol 
• 108-24-7 acetic anhydride 
• 112-62-9 Methyl oleate 
• 143-28-2 oleoyl alcohol 
• 693-80-1 oleyl acetate 
• 7642-09-3 cis-3-hexene 

Downstream Products

• 35148-19-7 (E)-9-dodecenyl acetate 

Relevant articles and documents

SYNTHESIS OF PHEROMONE DERIVATIVES VIA Z-SELECTIVE OLEFIN METATHESIS

Disclosed herein are methods for synthesizing fatty olefin metathesis products of high Z-isomeric purity from olefin feedstocks of low Z-isomeric purity. The methods include contacting a contacting an olefin metathesis reaction partner, such as acylated alkenol or an alkenal acetal, with an internal olefin in the presence of a Z-selective metathesis catalyst to form the fatty olefin metathesis product. In various embodiments, the fatty olefin metathesis products are insect pheromones. Pheromone compositions and methods of using them are also described.

Syntheses of the Sex Pheromone of the European Pine Shoot Moth (Rhyacionia buoliana). The Grignard Route

Grignard-Kopplungen zwischen zwei entsprechenden Synthonen fuehren zum (E)-9-Dodecen-1-ylacetat (1), dem Sexuallockstoff des Kiefernknospentriebwicklers (Rhyacionioa buoliana).Als solche Synthon-Paare wurden 1-Brom-(E)-2-penten (2) und 7-Bromheptyltetrahydropyranylether (3) bzw. (E)-3-Hexen-1-yltosylat (4) und 6-Bromhexyltrimethylsilylether (5) eingesetzt.Das Endprodukt (1) und die wichtigsten Zwischenprodukte wurden durch ihre 1H- und 13C-NMR-Spektren charakterisiert.Durch die zweite Synthese wurden 100percent Regio- und 99percent Stereoselektivitaet erreicht.