17024-04-3

Basic information

• Product Name: 9-(propan-2-yl)phenanthrene
• Synonyms: 9-Isopropylphenanthrene; phenanthrene, 9-(1-methylethyl)-
• CAS NO: 17024-04-3
• Molecular Formula: C₁₇H₁₆
• Molecular Weight: 220.3089
• Mol File: 17024-04-3.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 364.9°C at 760 mmHg
• Flash Point: 166.7°C
• Density: 1.06g/cm³
• Vapor Pressure: 3.43E-05mmHg at 25°C
• Refractive Index: 1.653
• CAS DataBase Reference: 9-(propan-2-yl)phenanthrene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-(propan-2-yl)phenanthrene(17024-04-3)
• EPA Substance Registry System: 9-(propan-2-yl)phenanthrene(17024-04-3)

Safety Data

• Hazardous Substances Data: 17024-04-3(Hazardous Substances Data)

Upstream product

• 2311-91-3 monoperoxyphthalic acid 
• 60-29-7 diethyl ether 
• 3274-03-1 toluene-4-sulfonic acid-(9-isopropyl-fluoren-9-ylmethyl ester) 
• 412322-31-7 2-biphenyl-2-yl-4-methyl-3-oxo-valeronitrile 
• 97634-15-6 9-isopropyl-9-(hydroxymethyl)fluorene 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 503-60-6 3,3-dimethyl-allyl chloride 
• 2039-77-2 9-acetylphenanthrene 
• 26878-12-6 ethyl fluorene-9-carboxylate 
• 97634-14-5 ethyl (9-isopropylfluoren-9-yl)carboxylate 
• 573-17-1 9-bromophenanthrene 
• 1888-75-1 isopropyllithium 
• 870-63-3 prenyl bromide 
• 108-86-1 bromobenzene 

Relevant articles and documents

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Preparation method of fused ring compound

The invention discloses a preparation method of a fused ring compound III. The preparation method comprises the following step: in a solvent and in the presence of palladium acetate, alkali and a ligand, carrying out a reaction shown in the specification on a compound I and a compound II to obtain a compound III. The preparation method disclosed by the invention is relatively good in compatibilitywith a substrate, various polycyclic aromatic hydrocarbon compounds can be simply obtained in a short period of time through convergent synthesis, and particularly, heteroatom-containing polycyclic aromatic hydrocarbon shows extremely excellent regioselectivity.

Pd(II)-NHDC-Functionalized UiO-67 Type MOF for Catalyzing Heck Cross-Coupling and Intermolecular Benzyne-Benzyne-Alkene Insertion Reactions

A novel palladium N-heterocyclic bis-carbene dicarboxylate ligand (Pd-NHDC-H2L) was successfully synthesized. In addition, an Pd-NHDC-containing UiO-67 type MOF (UiO-67-Pd-NHDC) was prepared on the basis of a size-matched ligand mixture of biphenyl-4,4′-dicarboxylic acid/Pd-NHDC-H2L (9/1) and ZrCl4 under solvothermal conditions. The obtained UiO-67-Pd-NHC MOF can be a highly heterogeneous catalyst to promote Heck cross-coupling and intermolecular benzyne-benzyne-alkene insertion reactions.

Polycyclic Aromatic Hydrocarbons via Iron(III)-Catalyzed Carbonyl-Olefin Metathesis

Polycyclic aromatic hydrocarbons are important structural motifs in organic chemistry, pharmaceutical chemistry, and materials science. The development of a new synthetic strategy toward these compounds is described based on the design principle of iron(III)-catalyzed carbonyl-olefin metathesis reactions. This approach is characterized by its operational simplicity, high functional group compatibility, and regioselectivity while relying on FeCl3 as an environmentally benign, earth-abundant metal catalyst. Experimental evidence for oxetanes as reactive intermediates in the catalytic carbonyl-olefin ring-closing metathesis has been obtained.