170307-14-9

Basic information

• Product Name: C₄H₂(NO₂)SCH₂OGe(C₆H₅)3
• CAS NO: 170307-14-9
• Molecular Weight: 462.065
• Mol File: 170307-14-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₄H₂(NO₂)SCH₂OGe(C₆H₅)3(CAS DataBase Reference)
• NIST Chemistry Reference: C₄H₂(NO₂)SCH₂OGe(C₆H₅)3(170307-14-9)
• EPA Substance Registry System: C₄H₂(NO₂)SCH₂OGe(C₆H₅)3(170307-14-9)

Safety Data

• Hazardous Substances Data: 170307-14-9(Hazardous Substances Data)

Upstream product

• 20898-85-5 (5-nitrothiophen-2-yl)methanol 
• 1626-24-0 chlorotriphenylgermane 

Relevant articles and documents

ETUDE DE NOUVELLES REACTIONS PAR TRANSFERT MONOELECTRONIQUE: ACTION D'ORGANOGERMYLLITHIUMS SUR LE FURFURAL, LE THIOPHENALDEHYDE ET LES DERIVES NITRES CORRESPONDANTS

The organogermyllithiums R3GeLi (R=Ph, Mes) were treated with several carbonyl conjugated substrates (2-furaldehyde, 2-thiophenecarboxaldehyde and their nitro-corresponding compounds).Only the germylation reactions of carbonyl group have been observed with a regioselectivity depending on the nature of the insaturated cycle.With 2-furaldehyde and 2-thiophenecarboxaldehyde, the germylcarbinols 1 are mainly obtained by C-germylation reaction.When an excess of aldehyde was used, the formation of germylketone 2 is surprisingly observed.With nitro compounds, the O-germylation reaction is preponderant.In this case, a single electron transfer mechanism takes place and was confirmed by ESR study.We observed the corresponding organic radical anion.The hyperfine structure of which has been resolved.Key words: SET reactions, germylation, radical anion, germyllithiums, germylketones, germanium centered radical.