17075-19-3

Basic information

• Product Name: 2-METHANESULFONYL-QUINOLINE
• Synonyms: 2-METHANESULFONYL-QUINOLINE;2-(Methylsulfonyl)quinoline
• CAS NO: 17075-19-3
• Molecular Formula: C₁₀H₉NO₂S
• Molecular Weight: 207.24896
• Mol File: 17075-19-3.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 428.154°C at 760 mmHg
• Flash Point: 212.74°C
• Appearance: /
• Density: 1.307g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.618
• CAS DataBase Reference: 2-METHANESULFONYL-QUINOLINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHANESULFONYL-QUINOLINE(17075-19-3)
• EPA Substance Registry System: 2-METHANESULFONYL-QUINOLINE(17075-19-3)

Safety Data

• Hazardous Substances Data: 17075-19-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H9NO2S/c1-14(12,13)10-7-6-8-4-2-3-5-9(8)11-10/h2-7H,1H3

Upstream product

• 40279-26-3 2-(methylthio)quinoline 
• 2637-37-8 Quinoline-2-thiol 
• 1613-37-2 Quinoline N-oxide 
• 20277-69-4 sodium methansulfinate 
• 91-22-5 quinoline 
• 612-62-4 2-Chloroquinoline 
• 6560-83-4 2-iodoquinoline 

Downstream Products

• 51369-80-3 2-(3-phenyl-oxiranyl)-quinoline 
• 877172-04-8 2-(2-bromo-4-methylanilino)quinoline 
• 877172-06-0 2-(2-bromo-4-methoxyanilino)quinoline 
• 877172-03-7 2-(2'-bromoanilino)quinoline 
• 205-54-9 quinolino<1,2-a>benzimidazole 
• 243-38-9 6H-quinindoline 

Relevant articles and documents

Modulation of photochemical oxidation of thioethers to sulfoxides or sulfones using an aromatic ketone as the photocatalyst

We have developed an eco-friendly and chemo-selective photocatalytic synthesis of sulfoxides or sulfones via oxidation of sulfides (thioethers) at ambient temperature using air or O2 as the oxidant. An inexpensive thioxanthone was used as the photocatalyst. Our method offers excellent chemical yields and good functional group tolerance. The hydrogen bonding between hexafluoro-2-propanol (HFIP) and sulfoxides may play an important role in minimizing the over-oxidization of sulfoxides.

Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation

An efficient protocol for the synthesis of 2-arylsulfonyl quinolines has been developed via a metal-free catalyzed cross-coupling reaction of chloroquinoline with sodium arylsulfinates in moderate-to-good yields under microwave irradiation. The reactions proceed with a wide range of substrates with good functional group tolerance.

Cu-Catalyzed Deoxygenative C2-Sulfonylation Reaction of Quinoline N-Oxides with Sodium Sulfinate

An unexpected Cu-catalyzed deoxygenative C2-sulfonylation reaction of quinoline N-oxides in the presence of radical initiator K2S2O8 was developed that used sodium sulfinate as a sulfonyl coupling partner. The mechanism studies indicate that the reaction proceeds via Minisci-like radical coupling step to give sulfonylated quinoline with good chemical yields.