17087-90-0

Basic information

• Product Name: Benzenamine, N,N-dimethyl-4-[[(4-methylphenyl)imino]methyl]-
• Synonyms: N-(4-(N,N-dimethylamino)benzal)-p-toluidine;4-Dimethylamino-benzaldehyd-p-tolylimin;N-(4-dimethylaminobenzylidene)-p-toluidine;N,N-dimethyl-4-((p-tolylimino)methyl)aniline;N-(4-Dimethylamino-benzyliden)-p-toluidin;HMS2292E11;4-Dimethylamino-benzaldehyd-p-tolylimid
• CAS NO: 17087-90-0
• Molecular Formula: C16H18N2
• Molecular Weight: 238.332
• Mol File: 17087-90-0.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzenamine, N,N-dimethyl-4-[[(4-methylphenyl)imino]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N,N-dimethyl-4-[[(4-methylphenyl)imino]methyl]-(17087-90-0)
• EPA Substance Registry System: Benzenamine, N,N-dimethyl-4-[[(4-methylphenyl)imino]methyl]-(17087-90-0)

Safety Data

• Hazardous Substances Data: 17087-90-0(Hazardous Substances Data)

Upstream product

• 106-49-0 p-toluidine 
• 1703-46-4 N,N-dimethyl-4-hydroxymethylaniline 
• 383408-85-3 diethyl ((4-tolylamino)(4-(dimethylamino)phenyl)methyl)phosphonate 
• 65423-89-4 triphenylarsazo-p-tolyl 
• 100-10-7 4-dimethylamino-benzaldehyde 
• 623-10-9 N-(4-methylphenyl)hydroxylamine 
• 121-69-7 N,N-dimethyl-aniline 

Downstream Products

• 100-10-7 4-dimethylamino-benzaldehyde 
• 127598-85-0 N-(4’-(N’,N’-dimethylamino)benzyl)-4-methylaniline 
• 41996-52-5 4-methylphenylamino-(1,3-dioxo-2,3-dihydro-1H-inden-2-ylidene)ethanenitrile 
• 62101-46-6 TW-69 
• 17123-20-5 2,5-bis (p-tolylamino)-3,6-dichlorocyclohexa-2,5-diene-1,4-dione 
• 140886-67-5 3-{5-[(4-Dimethylamino-phenyl)-p-tolylamino-methylsulfanyl]-2H-[1,2,4]triazol-3-yl}-chromen-2-one 
• 29027-08-5 2,5-di(p-tolyl)amino-3,6-dibromo-1,4-benzoquinone 
• 3915-61-5 2-[4-(dimethylamino)styryl]-1-methylquinolinium iodide 

Relevant articles and documents

Thermodynamic study for the stability of aromatic complexes formation derived from the reaction of 4-dimethyl amino benzaldehyde with diazotized dinitro aniline reagents

This research includes the preparation of aromatic azoimine complexes resulting from the coupling reaction (4) of Schiff bases with diazotized dinitroaniline reagent. Ultraviolet spectra, infrared spectra, and melting points are among the most important p

Divergent Coupling of Alcohols and Amines Catalyzed by Isoelectronic Hydride MnIand FeIIPNP Pincer Complexes

Herein, we describe an efficient coupling of alcohols and amines catalyzed by well-defined isoelectronic hydride MnIand FeIIcomplexes, which are stabilized by a PNP ligand based on the 2,6-diaminopyridine scaffold. This reaction is an environmentally benign process implementing inexpensive, earth-abundant non-precious metal catalysts, and is based on the acceptorless alcohol dehydrogenation concept. A range of alcohols and amines including both aromatic and aliphatic substrates were efficiently converted in good to excellent isolated yields. Although in the case of Mn selectively imines were obtained, with Fe—exclusively monoalkylated amines were formed. These reactions proceed under base-free conditions and required the addition of molecular sieves.

Synthesis and NMR characterization of two novel anthracene-derived BIS-aminophosphonates. Basic hydrolysis of some aminophosphonate derivatives

The synthesis of two novel bis-aminophosphonates bearing anthracene rings-bis[N-methyl(diethoxyphosphonyl)-1-(9-anthryl)]benzidine (3) and 4,4-bis[N-methyl(diethoxy-phosphonyl)-1-(9-anthryl)]diaminodiphenylmethane (4)-via the Kabachnik-Fields reaction is reported. The compounds have been characterized by elemental analysis, TLC, IR, NMR (1H, 13C, 31P) and fluorescent spectra. The reaction leads to a mixture of the two possible forms (meso and racemic), with predominant formation of one of the diastereomers. The recrystallized compounds 3 and 4 consist of only one diastereomer. A racemization at the chiral centers and a cleavage of the C-P bond are observed in the alkaline hydrolysis of the new compound 4 and three previously described aminophosphonate derivatives 5-7. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.