170938-18-8

Basic information

• Product Name: Carbonic acid, 1-(4-bromophenyl)-2-propenyl methyl ester
• CAS NO: 170938-18-8
• Molecular Formula: C11H11BrO3
• Molecular Weight: 271.111
• Mol File: 170938-18-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Carbonic acid, 1-(4-bromophenyl)-2-propenyl methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid, 1-(4-bromophenyl)-2-propenyl methyl ester(170938-18-8)
• EPA Substance Registry System: Carbonic acid, 1-(4-bromophenyl)-2-propenyl methyl ester(170938-18-8)

Safety Data

• Hazardous Substances Data: 170938-18-8(Hazardous Substances Data)

Upstream product

• 1826-67-1 vinyl magnesium bromide 
• 1122-91-4 4-bromo-benzaldehyde 
• 79-22-1 methyl chloroformate 
• 58824-56-9 1-(p-bromophenyl)prop-2-en-1-ol 

Downstream Products

• 1464149-52-7 (E)-(3-(4-bromophenyl)allyl)(trifluoromethyl)sulfane 

Relevant articles and documents

Cobalt-Catalyzed Allylic Alkylation Enabled by Organophotoredox Catalysis

Co-catalyzed allylic substitution reactions have received little attention, arguably because of the lack of any known advantage of Co catalysis over either Rh or Ir catalysis. Described here is a general and regioselective Co-catalyzed allylic alkylation using an in situ catalyst activation by organophotoredox catalysis. This noble-metal-free catalytic system exhibits unprecedentedly high reactivities and regioselectivities for the allylation with an allyl sulfone, for the first time, representing the unique synthetic utility of the Co-catalyzed method compared to the related Rh- and Ir-catalyzed reactions.

Regio- and enantioselective synthesis of chiral pyrimidine acyclic nucleosides via rhodium-catalyzed asymmetric allylation of pyrimidines

A direct route to branched N-allylpyrimidine analogues is herein reported via the highly regio- and enantioselective asymmetric allylation of pyrimidines with racemic allylic carbonates. With [Rh(COD)Cl]2/chiral diphosphine as the catalyst, a r

Regiocontrol and Stereoselectivity in Tungsten-Bipyridine Catalysed Allylic Alkylation

Tungsten-bipyridine complexes, generated in situ, catalyse the allylic alkylation of isocinnamyl methyl carbonate by dimethyl sodiomalonate with complete syn-stereoselectivity.When para substituted aryl-allyl methyl carbonates are employed, the regioselectivity correlates with Swain-Lupton parameters.Cross-over experiments demonstrate that the reactions do not proceed via the conventional 0> -> II allyl>+ -> 0 allyl-Nu> catalytic cycle.