170940-99-5

Basic information

• Product Name: di-(+)-menthyl diazane-1,2-dicarboxylate
• Synonyms: di-(+)-menthyl diazane-1,2-dicarboxylate
• CAS NO: 170940-99-5
• Molecular Weight: 396.571
• Mol File: 170940-99-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: di-(+)-menthyl diazane-1,2-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: di-(+)-menthyl diazane-1,2-dicarboxylate(170940-99-5)
• EPA Substance Registry System: di-(+)-menthyl diazane-1,2-dicarboxylate(170940-99-5)

Safety Data

• Hazardous Substances Data: 170940-99-5(Hazardous Substances Data)

Upstream product

• 7635-54-3 (+)-(1S,2R,5S)-menthylchloroformate 

Downstream Products

• 170940-97-3 di-(+)-menthyl diazenedicarboxylate 

Relevant articles and documents

Synthesis of chiral diazanedicarboxylate and diazenedicarboxylate esters: electrophilic amination reactions of achiral ester and amide enolates

A series of chiral dialkyl (bornyl, isobornyl, menthyl) diazenedicarboxylates 4a-c were prepared by conversion of the corresponding alcohols into chloroformates, condensation with hydrazine, and oxidation of the corresponding dialkyl diazanedicarboxylates 3a-c with N-bromosuccinimide and pyridine (50-90percent yield).Their reaction with achiral enolates of esters and N,N-dimethyl amides at -70 deg C gave α-hydrazino acid derivatives with little or no stereoselectivity.Analogous amination of chiral oxazolidinone (Evans enolate) anions were highly selective, but were controlled exclusively by enolate geometry.