17106-33-1Relevant articles and documents
Highly selective hydrosilylation of olefins and acetylenes by platinum(0) complexes bearing bulky N-heterocyclic carbene ligands
Zak,Bo?t,Kubicki,Pietraszuk
supporting information, p. 1903 - 1910 (2018/02/17)
Platinum complexes bearing bulky N-heterocyclic carbene (NHC) ligands, i.e., [Pt(IPr?)(dvtms)] (where, IPr? = 1,3-bis{2,6-bis(diphenylmethyl)-4-methylphenyl}imidazol-2-ylidene) and [Pt(IPr?OMe)(dvtms)] (where, IPr?OMe = 1,3-bis{2,6-bis(diphenylmethyl)-4-m
Visible-Light-Mediated Metal-Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si?H Activation
Zhou, Rong,Goh, Yi Yiing,Liu, Haiwang,Tao, Hairong,Li, Lihua,Wu, Jie
supporting information, p. 16621 - 16625 (2017/12/13)
Although there has been significant progress in the development of transition-metal-catalyzed hydrosilylations of alkenes over the past several decades, metal-free hydrosilylation is still rare and highly desirable. Herein, we report a convenient visible-
METHOD FOR PRODUCING ORGANOSILICON COMPOUND AND CATALYST COMPOSITION
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Paragraph 0031; 0032, (2016/12/01)
PROBLEM TO BE SOLVED: To provide a method for producing an organosilicon compound by the hydrosilylation reaction of alkenes or alkynes using a new catalyst. SOLUTION: There is provided a method for producing an organosilicon compound in which a nickel complex compound represented by the following formula and a borane compound such as tri(pentafluorophenyl)borane or a hydride reducing agent such as sodium triethylhydroborate are blended in a reaction solution in the hydrosilylation reaction of alkenes such as 1-octene and butadiene or alkynes. (R1 each independently represents H or a hydrocarbon group having 1 to 15 carbon atoms substituted/unsubstituted with at least one atom selected from N, O, S or a halogen atom.) COPYRIGHT: (C)2016,JPOandINPIT