172215-49-5Relevant articles and documents
Synthesis and reactions of organic compounds with a nitrogen atom. Part XVII. Reactions of acyclic and monocyclic chlorides with phenyltelluro- and phenylselenosodium
Bakowska-Janiszewska,Scianowski,Uzarewicz
, p. 649 - 656 (2007/10/03)
The reaction of neryl (3), geranyl (4), (+)-carvotanacetyl (5), (-)-carvyl (6) and perillyl (7) chlorides with phenylseleno-(1) or phenyltellurosodium (2), and then with chloramine-T afforded α,β-unsaturated toluenesulfonamides 8-11, which were reduced with sodium in liquid ammonia to allylic amines 12-15. Allylic phenyltellurides were oxidized by air to carbonyl compounds 29-31 or alcohol 28.