172471-62-4Relevant articles and documents
Facile Diastereoseparation of Glycosyl Sulfoxides by Chiral Stationary Phase
Taniguchi, Tohru,Asahata, Mai,Nasu, Akihito,Shichibu, Yukatsu,Konishi, Katsuaki,Monde, Kenji
supporting information, p. 534 - 539 (2016/07/28)
Separation of the diastereomers of glycosyl sulfoxides differing in the sulfur chirality has been difficult. This article presents a fast and scalable method for their diastereoseparation using a chiral stationary phase. The usefulness of this method was
Sulfenate intermediates in the sulfoxide glycosylation reaction
Gildersleeve, Jeff
, p. 5961 - 5969 (2007/10/03)
The sulfoxide glycosylation reaction works remarkably well for many difficult glycosylations. We attribute this in part to the fact that an extremely reactive intermediate can be generated rapidly under mild conditions at low temperature. We find that ano