17270-06-3Relevant articles and documents
Cation radical chain cycloaddition polymerization: A fundamentally new polymerization mechanism
Bauld, Nathan L.,Gao, Daxin,Aplin, J. Todd
, p. 808 - 818 (2007/10/03)
Cation radical chain cycloaddition polymerization, a fundamentally new addition polymerization method involving cation radical intermediates in each propagation step, is described and demonstrated. The cycloaddition reactions of appropriately constituted
Lewis Acid Mediated Claisen-Type Rearrangement of Aryl Dienyl Ethers
Maruyama, Kazuhiro,Nagai, Naoshi,Naruta, Yoshinori
, p. 5083 - 5092 (2007/10/02)
Rearrangement of aryl pentadienyl ethers in the presence of BF3*OEt2 affords pentadienyl phenols in good yields without formation of the corresponding rearranged products.The mechanism of this rearrangement was studied by deuterium labeling and cross-coupling reactions.The scope and limitations of the rearrangement are discussed.