172700-47-9

Basic information

• Product Name: Benzyl-[1-(2-bromo-pyridin-3-yl)-meth-(E)-ylidene]-amine
• Synonyms: Benzyl-[1-(2-bromo-pyridin-3-yl)-meth-(E)-ylidene]-amine
• CAS NO: 172700-47-9
• Molecular Weight: 275.148
• Mol File: 172700-47-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzyl-[1-(2-bromo-pyridin-3-yl)-meth-(E)-ylidene]-amine(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyl-[1-(2-bromo-pyridin-3-yl)-meth-(E)-ylidene]-amine(172700-47-9)
• EPA Substance Registry System: Benzyl-[1-(2-bromo-pyridin-3-yl)-meth-(E)-ylidene]-amine(172700-47-9)

Safety Data

• Hazardous Substances Data: 172700-47-9(Hazardous Substances Data)

Upstream product

• 128071-75-0 2-bromopyridine-3-carboxaldehyde 
• 100-46-9 benzylamine 

Downstream Products

• 59397-80-7 3-benzyl-1-phenyl-3,4-dihydropyrido[2,3-d]pyrimidin-2(1H)-one 
• 622851-57-4 N-benzyl-N-[(2-bromopyridin-3-yl)methyl]amine 

Relevant articles and documents

Ligandless Nickel-Catalyzed Ortho-Selective Directed Trifluoromethylthiolation of Aryl Chlorides and Bromides Using AgSCF3

A mild protocol for Ni-catalyzed trifluoromethylthiolation of aryl chlorides and bromides is described herein. The method utilizes AgSCF3 as an easily accessible nucleophilic trifluoromethylthiolating reagent and does not require any ligands or additives. Ortho-selectivity is achieved using a variety of directing groups such as imines, pyridines, and oxazolines for 24 examples in up to 95% yield.