172877-31-5Relevant articles and documents
Stereocontrolled Intramolecular Michael-Aldol Reaction Mediated with Bu2BOTf and (TMS)2NH
Ihara, Masataka,Taniguchi, Takahiko,Yamada, Masami,Tokunaga, Yuji,Fukumoto, Keiichiro
, p. 8071 - 8074 (2007/10/02)
Treatment of keto-esters 1-5 with Bu2BOTf and (TMS)2NH caused a tandem Michael-aldol reaction to give polycyclic cyclobutanes 6-10 with high stereoselection.It was proved that the reaction was accelerated by the addition of Bu4NI.