17310-79-1

Basic information

• Product Name: Diazene, (4-methylphenyl)phenyl-, 2-oxide
• CAS NO: 17310-79-1
• Molecular Formula: C13H12N2O
• Molecular Weight: 212.251
• Mol File: 17310-79-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Diazene, (4-methylphenyl)phenyl-, 2-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: Diazene, (4-methylphenyl)phenyl-, 2-oxide(17310-79-1)
• EPA Substance Registry System: Diazene, (4-methylphenyl)phenyl-, 2-oxide(17310-79-1)

Safety Data

• Hazardous Substances Data: 17310-79-1(Hazardous Substances Data)

Upstream product

• 106-49-0 p-toluidine 
• 586-96-9 Nitrosobenzene 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 16046-28-9 N'-p-Toluolsulfonyloxy-N-phenyl-diimid-N-oxid 
• 16046-28-9 N-Phenyl-N'-tosyloxydiimid-N-oxid 
• 17310-78-0 β-p-methylazoxybenzene 
• 949-87-1 4-Methylazobenzol 
• 98-95-3 nitrobenzene 

Downstream Products

• 582-85-4 5-Methyl-2-phenylazo-phenol 
• 20773-92-6 2-p-Tolylazo-phenol 
• 2497-33-8 4-((4-methylphenyl)azo)phenol 
• 96217-83-3 N'-(4-bromo-phenyl)-N-p-tolyl-diazene-N-oxide 
• 949-87-1 4-Methylazobenzol 
• 111078-57-0 4-phenyl-ONN-azoxybenzoic acid 

Relevant articles and documents

Synthesis of Unsymmetrical Azoxyarenes via Copper-Catalyzed Aerobic Oxidative Dehydrogenative Coupling of Anilines with Nitrosoarenes

A copper-catalyzed oxidative dehydrogenative coupling of nitrosobenzenes with anilines for the synthesis of unsymmetrical azoxybenzenes was developed. This approach uses O2 as the oxidant. The reaction products are diverse unsymmetrical azoxybe

Rh(III)-Catalyzed [4 + 1]-Annulation of Azoxy Compounds with Alkynes: A Regioselective Approach to 2H-Indazoles

A rhodium-catalyzed regioselective C-H activation/cyclization of azoxy compounds with alkynes has been disclosed to construct a variety of 2H-indazoles. A [4 + 1]-cycloaddition rather than a normal [4 + 2] mode is observed in the process of cyclative capture along with an oxygen-atom transfer and a C≡C triple bond cleavage. This protocol features a broad substrate scope, a good functional group tolerance, and an exclusive regioselectivity.

Aryliminodimagnesium Reagents. IV. The Independent Preparation of Unsymmetrically Substituted Azoxyarene Isomers and Their Deoxygenation

By use of the condensation reaction of aryliminodimagnesium reagents (ArN(MgBr)2) with nitroarenes, six symmetrical and eight unsymmetrical azoxyarenes including four pairs of isomers were prepared in 40-80percent yields.The deoxygenation reaction of the azoxyarenes by treating with five molar equivalents of p-MeOC6H4N(MgBr)2 at 55 deg C in tetrahydrofuran was also studied, and the reactivity of deoxygenation was correlated to the shift of the electronic absorption maximum of azoxyarene.