173142-22-8

Basic information

• Product Name: 1,5-Dichloro-4,8-diphenyltricyclo[5.1.0.0^3,5]octane-2,6-dione
• Synonyms: 1,5-Dichloro-4,8-diphenyltricyclo[5.1.0.0^3,5]octane-2,6-dione
• CAS NO: 173142-22-8
• Molecular Weight: 357.236
• Mol File: 173142-22-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,5-Dichloro-4,8-diphenyltricyclo[5.1.0.0^3,5]octane-2,6-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-Dichloro-4,8-diphenyltricyclo[5.1.0.0^3,5]octane-2,6-dione(173142-22-8)
• EPA Substance Registry System: 1,5-Dichloro-4,8-diphenyltricyclo[5.1.0.0^3,5]octane-2,6-dione(173142-22-8)

Safety Data

• Hazardous Substances Data: 173142-22-8(Hazardous Substances Data)

Upstream product

• 75-09-2 dichloromethane 
• 4192-77-2 ethyl cinnamate 
• 103-26-4 Methyl cinnamate 
• 31416-74-7 i-butyl (E)-3-phenyl-2-propenoate 
• 74513-58-9 (E)-propyl cinnamate 
• 52392-64-0 (E)-3-(phenyl)acrylic acid butyl ester 
• 17377-82-1 (E)-1-methylpropyl cinnamate 
• 60512-85-8 (E)-isopropyl cinnamate 
• 55629-90-8 (3E)‐1,1‐dichloro‐4‐phenylbut‐3‐en‐2‐one 

Downstream Products

• 108196-55-0 2,5-bisbenzyl-1,4-benzoquinone 

Relevant articles and documents

A novel synthesis of tricyclo[5.1.0.03,5]octane-2,6-dione derivatives via double Michael addition-induced cyclopropanation reactions

Tricyclo[5.1.0.03,5]octane-2,6-diones 1a-q were prepared in moderate yields by the reaction of α,β-unsaturated esters 2 with dihalomethane in the presence of butyllithium, and by the reaction of dichloromethyl α,β-unsaturated ketones 3 with sodium ethoxide, respectively. This reaction was newly explained by a mechanism involving intermolecular double Michael additions of enolate anion 4 of ketones 3 and the following cyclopropanation.