173166-52-4

Basic information

• Product Name: 1,3,5-Triphosphorin, 2,4,6-tris(1,1-dimethylethyl)-
• CAS NO: 173166-52-4
• Molecular Formula: C15H27P3
• Molecular Weight: 300.301
• Mol File: 173166-52-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1,3,5-Triphosphorin, 2,4,6-tris(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-Triphosphorin, 2,4,6-tris(1,1-dimethylethyl)-(173166-52-4)
• EPA Substance Registry System: 1,3,5-Triphosphorin, 2,4,6-tris(1,1-dimethylethyl)-(173166-52-4)

Safety Data

• Hazardous Substances Data: 173166-52-4(Hazardous Substances Data)

Upstream product

• 78129-68-7 2,2-dimethylpropylidynephosphine 
• 101055-70-3 1-adamantylphosphaacetylene 

Downstream Products

• 161689-77-6 2,4,6,7-Tetra-tert-butyl-1,3,5,8-tetraphospha-bicyclo[2.2.2]octa-2,5,7-triene 
• 864069-71-6 [(COD)Rh(η6-P3C3Bu(t)3)][B(C6H3(CF3)2-3,5)4] 
• 243960-77-2 trans-PtCl₂(PMe₂Ph)(2,4,6-tritertiarybutyl-1,3,5-triphosphabenzene 
• 913341-80-7 [Ph3Sn(η2-P,P-MeP3C3(t-Bu)3)] 
• 913341-82-9 [Ph3Pb(η2-P,P-MeP3C3(t-Bu)3)] 
• 913341-76-1 [((C₆H₁₁)2NC(NC₆H₃(CH(CH₃)2)2)2)Sn(P₂C₃(C(CH₃)3)3)] 
• 913341-77-2 [((cis-2,6-Me₂C₅H₈N)C(NC₆H₃(i-Pr)2-2,6)2)Sn(P₂C₃(t-Bu)3)] 
• 243960-78-3 C₃P₃[C(CH₃)3]3PtCl₂PCH₃(C₆H₅)2 
• 93756-84-4 5-tert-Butyl-3-mesityl-1,2,4-oxazaphosphol 
• 101028-91-5 5-tert-butyl-3-phenyl-1,2,4-oxazaphosphole 

Relevant articles and documents

Hydrogen activation by an aromatic triphosphabenzene

Aromatic hydrogenation is a challenging transformation typically requiring alkali or transition metal reagents and/or harsh conditions to facilitate the process. In sharp contrast, the aromatic heterocycle 2,4,6-tri-tert -butyl-1,3,5-triphosphabenzene is shown to be reduced under 4 atm of H2 to give [3.1.0]bicylo reduction products, with the structure of the major isomer being confirmed by X-ray crystallography. NMR studies show this reaction proceeds via a reversible 1,4-H2 addition to generate an intermediate species, which undergoes an irreversible suprafacial hydride shift concurrent with P - P bond formation to give the isolated products. Further, para-hydrogen experiments confirmed the addition of H2 to triphosphabenzene is a bimolecular process. Density functional theory (DFT) calculations show that facile distortion of the planar triphosphabenzene toward a boat-conformation provides a suprafacial combination of vacant acceptor and donor orbitals that permits this direct and uncatalyzed reduction of the aromatic molecule.

The metal-initiated cyclooligomerization of phospha-alkynes and its consequences [1]

1,3-Diphosphacyclobutadienes 4 are almost certainly intermediates in the conversion by hexachloroethane of phosphaalkyne dimer complexes 3 to the tetraphosphacubanes 5. We now describe trapping reactions of 4, generated in the same way, wilh phosphaalkyne 1 (→9), ynamines 10 (→13), and electron-poor alkynes 11 (→14). The cyclooligomerization of 1 initiated by t-Bu-N=VCl3·DME (15) leads to the azatetraphosphaquadricyclanes 20 while the reaction with the stronger Lewis acid t-Bu-N=VCl3 (21) furnishes the 1,3,5-triphosphabenzenes 23 in high selectivity.

η8-cyglooctatetraene metal complexes, a new class of templates for phosphaalkyne cyclooligomerizations

For the first time selective cyclodi-, tri-, and tetramerization of phosphaalkynes are induced by an unique class of transition metal complexes by changing the reaction conditions.