1733-62-6

Basic information

• Product Name: Benzophenone 2,4-dinitrophenyl hydrazone
• Synonyms: Benzophenone 2,4-dinitrophenyl hydrazone
• CAS NO: 1733-62-6
• Molecular Formula: C₁₉H₁₄N₄O₄
• Molecular Weight: 362.3389
• Mol File: 1733-62-6.mol
• Article Data: 18

Chemical Properties

• Boiling Point: 530.8°Cat760mmHg
• Flash Point: 274.8°C
• Appearance: /
• Density: 1.32g/cm³
• Vapor Pressure: 2.37E-11mmHg at 25°C
• Refractive Index: 1.652
• CAS DataBase Reference: Benzophenone 2,4-dinitrophenyl hydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: Benzophenone 2,4-dinitrophenyl hydrazone(1733-62-6)
• EPA Substance Registry System: Benzophenone 2,4-dinitrophenyl hydrazone(1733-62-6)

Safety Data

• Hazardous Substances Data: 1733-62-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C19H14N4O4/c24-22(25)16-11-12-17(18(13-16)23(26)27)20-21-19(14-7-3-1-4-8-14)15-9-5-2-6-10-15/h1-13,20H

Upstream product

• 64-17-5 ethanol 
• 29586-02-5 N²-nitroso-1,1,N²-triphenyl-methanon hydrazone 
• 76368-93-9 benzophenone (2-nitrophenyl)hydrazone 
• 2675-31-2 benzophenone-(4-nitro-phenylhydrazone) 
• 574-61-8 benzophenone N-phenylhydrazone 
• 102478-11-5 2,2-diphenylvinyl 4-methylbenzenesulfonate 
• 119-61-9 benzophenone 
• 119-26-6 (2,4-dinitro-phenyl)-hydrazine 
• 71-43-2 benzene 
• 110-46-3 isopentyl nitrite 
• 76195-86-3 2,4-dinitrophenylhydrazine hydrochloride 
• 76-93-7 Benzilic acid 
• 464-72-2 tetraphenylethane-1,2-diol 
• 86451-26-5 2,2'-(phenyl-λ³-iodanediyl)bis(isoindoline-1,3-dione) 

Downstream Products

• 119-61-9 benzophenone 
• 360-11-2 difluorodiphenylmethane 
• 615-71-4 benzene-1,2,4-triamine 

Relevant articles and documents

Hydrogen Bonding in Phenylhydrazone Derivatives of Benzophenone: Crystal and Molecular Structures of Benzophenone (2-Nitrophenyl)hydrazone, containing an Intramolecular NO2...NH...? Bifurcated Hydrogen Bond, and Benzophenone (4-Nitrophenyl)hydrazone, cont

Crystal structures have been determined of the two title compounds.The (2-nitrophenyl)hydrazone (2) is monoclinic, space group P21/a, Z = 4, with a = 12.074(5), b = 12.771(8), c = 11.998(8) Angstroem, β = 118.0 deg.The (4-nitrophenyl)hydrazone

Oxidation of benzhydrol by tetrabutylammoniumbromochromate in presence and absence of picolinic acid and 1,10-phenanthroline: A kinetic study

The oxidation of benzhydrol (BH) by tetrabutylammoniumbromochromate (TBABC) was studied in aqueous acetic acid medium. The reaction is first order with respect to tetrabutylammoniumbromochromate, benzhydrol and [H+] and the reaction is catalyzed by hydrogen ions. The reaction has been studied in the presence of picolinic acid and 1,10-phenanthroline as promoters. The promoters used in this oxidation reaction, picolinic acid and 1,10-phenanthroline are strong chelating ligands which form complexes with most transition metal ions. Among the two promoters oxidation is much faster with 1,10-phenanthroline. The low dielectric constant of the medium assists the complex formation and enhances the reactivity. The reactions were studied at different temperatures at different acetic acid-water composition and various thermodynamic parameters have been determined. The observed experimental results have been explained by plausible mechanisms.

Oxidative cleavage and rearrangement of aryl epoxides using iodosylbenzene: On criegee's trail

Aryl epoxides undergo rearrangement and oxidative cleavage when reacted with in situ prepared hydroxy-λ3-iodane complexes. The presence of H2O plays a decisive role in steering the reaction path. A mechanistic scheme is proposed that accounts for the observed chemoselectivities. Copyright