173458-34-9Relevant articles and documents
Visible light sensitization of benzoyl azides: Cascade cyclization toward oxindoles: Via a non-nitrene pathway
Bagal, Dattatraya B.,Park, Sung-Woo,Song, Hyun-Ji,Chang, Sukbok
supporting information, p. 8798 - 8801 (2017/08/09)
Visible light sensitization of benzoyl azides was examined in reaction with N-phenylmethacrylamides to afford biologically important oxindoles and spirooxindoles via a cascade cyclization under mild reaction conditions. Mechanistic studies suggested a non-nitrene pathway, where triplet benzoyl azides act as the reactive intermediate.
Oxidative amidation and azidation of aldehydes by NHC catalysis
De Sarkar, Suman,Studer, Armido
supporting information; experimental part, p. 1992 - 1995 (2010/07/10)
Figure presented N-Heterocyclic carbene catalyzed oxidative amidations of various aldehydes to the corresponding hexafluoroisopropylesters by using the readily available organic oxidant A are described. The hexafluoroisopropylesters prepared in situ are shown to be highly useful active esters for amide bond formation. In addition, oxidative azidation of aldehydes is presented. These mild organocatalytic processes do not use any transition metal.
