173536-82-8

Basic information

• Product Name: tert-Butyl-diphenyl-[(2E,4E)-7-(tetrahydro-pyran-2-yloxy)-hepta-2,4-dienyloxy]-silane
• CAS NO: 173536-82-8
• Molecular Weight: 450.693
• Mol File: 173536-82-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-Butyl-diphenyl-[(2E,4E)-7-(tetrahydro-pyran-2-yloxy)-hepta-2,4-dienyloxy]-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-diphenyl-[(2E,4E)-7-(tetrahydro-pyran-2-yloxy)-hepta-2,4-dienyloxy]-silane(173536-82-8)
• EPA Substance Registry System: tert-Butyl-diphenyl-[(2E,4E)-7-(tetrahydro-pyran-2-yloxy)-hepta-2,4-dienyloxy]-silane(173536-82-8)

Safety Data

• Hazardous Substances Data: 173536-82-8(Hazardous Substances Data)

Upstream product

• 149650-06-6 (E,E)-ethyl 7-tetrahydropyranyloxy-2,4-heptadienoate 
• 115524-30-6 (E)-5-(Tetrahydro-pyran-2-yloxy)-pent-2-enal 
• 92844-99-0 (2E)-5-<(2-tetrahydropyranyl)oxy>pent-2-en-1-ol 
• 149310-67-8 ethyl (E)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-2-enoate 
• 2162-33-6 3-(tetrahydropyran-2-yloxy)propan-1-ol 
• 62592-78-3 3-(2-tetrahydropyranyloxy)propanal 
• 110-87-2 3,4-dihydro-2H-pyran 
• 149311-09-1 (2E,4E)-7-(Tetrahydro-pyran-2-yloxy)-hepta-2,4-dien-1-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 173537-02-5 2-[(3E,5E)-7-(tert-Butyl-diphenyl-silanyloxy)-hepta-3,5-dienyl]-2-((E)-6-methanesulfonyloxy-4-methyl-hex-3-enyl)-malonic acid dimethyl ester 
• 173537-00-3 (E,E,E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-1-tetrahydropyranyloxy-tetradeca-3,10,12-triene 
• 173537-01-4 (E,E,E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-tetradeca-3,10,12-trien-1-ol 
• 173537-03-6 (5E,12E,14E)-16-(tert-Butyl-diphenyl-silanyloxy)-2,9,9-tris-methoxycarbonyl-5-methyl-hexadeca-5,12,14-trienoic acid methyl ester 
• 173537-08-1 (3Z,10E,12E)-3-(methoxymethoxy)methyl-1-acetoxy-7,7-bis(methoxycarbonyl)-14-tert-butyldiphenylsiloxytetradeca-3,10,12-triene 
• 173536-83-9 Methanesulfonic acid (3E,5E)-7-(tert-butyl-diphenyl-silanyloxy)-hepta-3,5-dienyl ester 
• 173537-11-6 (4Z,11E,13E)-4-(methoxymethoxy)methyl-1,1,8,8-tetrakis(methoxycarbonyl)-15-tert-butyldiphenylsiloxypentadeca-4,11,13-triene 
• 173537-10-5 2-[(3E,5E)-7-(tert-Butyl-diphenyl-silanyloxy)-hepta-3,5-dienyl]-2-((Z)-6-methanesulfonyloxy-4-methoxymethoxymethyl-hex-3-enyl)-malonic acid dimethyl ester 
• 173656-65-0 (5Z,12E,14E)-16-(tert-Butyl-diphenyl-silanyloxy)-2,9,9-tris-methoxycarbonyl-5-methyl-hexadeca-5,12,14-trienoic acid methyl ester 
• 173656-67-2 2-[(3E,5E)-7-(tert-Butyl-diphenyl-silanyloxy)-hepta-3,5-dienyl]-2-((Z)-6-methanesulfonyloxy-4-methyl-hex-3-enyl)-malonic acid dimethyl ester 
• 173656-68-3 (3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-1-tetrahydropyranyloxy-tetradeca-3,10,12-triene 
• 173537-09-2 (3Z,10E,12E)-3-(methoxymethoxy)methyl-7,7-bis(methoxycarbonyl)-14-tert-butyldiphenylsiloxytetradeca-3,10,12-trienol 
• 173656-64-9 (3Z,10E,12E)-3-methyl-14-tert-butyldiphenylsiloxy-7,7-bis(methoxycarbonyl)-tetradeca-3,10,12-trienol 
• 173536-84-0 (E,E)-8-tert-butyldiphenylsiloxy-1,1-bis(methoxycarbonyl)-4,6-octadiene 

Relevant articles and documents

Studies on the transannular Diels-Alder reaction of 15-membered macrocyclic trienes containing a trans-trans diene. Part I: Synthesis and isomerization of various model cyclopentadecatrienes

The transannular Diels-Alder reaction of 15-membered macrocyclic trienes with a trans-trans-cis (TTC) olefin geometry can lead to A.B.C. tricyclic products of trans-syn-trans (TST) and cis-syn-cis (CSC) stereochemistry whereas the TTT isomers can p