174584-85-1

Basic information

• Product Name: [RuCl(CO)(P(C₆H₅)3)2(NHC(C₆H₅)NC(C₆H₅)O)]
• CAS NO: 174584-85-1
• Molecular Weight: 912.369
• Mol File: 174584-85-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [RuCl(CO)(P(C₆H₅)3)2(NHC(C₆H₅)NC(C₆H₅)O)](CAS DataBase Reference)
• NIST Chemistry Reference: [RuCl(CO)(P(C₆H₅)3)2(NHC(C₆H₅)NC(C₆H₅)O)](174584-85-1)
• EPA Substance Registry System: [RuCl(CO)(P(C₆H₅)3)2(NHC(C₆H₅)NC(C₆H₅)O)](174584-85-1)

Safety Data

• Hazardous Substances Data: 174584-85-1(Hazardous Substances Data)

Upstream product

• 157072-60-1 (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 7732-18-5 water 
• 100-47-0 benzonitrile 

Relevant articles and documents

Formation of N-imidoylimidatoruthenium(II) complexes via ruthenium-promoted hydration of nitriles

The hydridoruthenium(II) complex [RuCl(H)(CO)(PPh3)3] 1 reacted with aromatic nitriles at 120°C in the presence of water to give novel N-imidoylimidatoruthenium(II) complexes [RuCl(NH=CRN=CRO)(CO)(PPh3)2] (R = C6H4Me-p 2, Ph 3, or C6H4Me-m 4). In contrast, reaction of o-toluonitrile with 1 gave a small amount of the corresponding N-imidoylimidato complex and a considerable amount of o-toluamide. When 1 was heated at 120°C in a 1:1 mixture of an amide R1CONH2 and a nitrile R2CN a cross-linked N-imidoylimidato complex [RuCl(NH=CR2N=CR1O)(CO)(PPh3)2] 6 (R1 = Ph, R2 = C6H4Me-p) or 7 (R1 = C6H4Me-p, R2 = Ph) was obtained. Single-crystal structure analyses of 2 and 6 have been performed.