17515-18-3

Basic information

• Product Name: 1-Cyclohexene-1-carboxylic acid, 3,4,5-tris(acetyloxy)-, methyl ester, (3R,4S,5R)-
• CAS NO: 17515-18-3
• Molecular Formula: C14H18O8
• Molecular Weight: 314.292
• Mol File: 17515-18-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-Cyclohexene-1-carboxylic acid, 3,4,5-tris(acetyloxy)-, methyl ester, (3R,4S,5R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexene-1-carboxylic acid, 3,4,5-tris(acetyloxy)-, methyl ester, (3R,4S,5R)-(17515-18-3)
• EPA Substance Registry System: 1-Cyclohexene-1-carboxylic acid, 3,4,5-tris(acetyloxy)-, methyl ester, (3R,4S,5R)-(17515-18-3)

Safety Data

• Hazardous Substances Data: 17515-18-3(Hazardous Substances Data)

Upstream product

• 191916-39-9 methyl (-)-quinate 
• 96290-97-0 (2R,3R,4S,5R)-2,3,4,5-Tetraacetoxy-cyclohexane-1,1-dicarboxylic acid dimethyl ester 
• 96236-38-3 (2S,3R,4S,5R)-2,3,4,5-Tetraacetoxy-cyclohexane-1,1-dicarboxylic acid dimethyl ester 
• 108-24-7 acetic anhydride 
• 120586-32-5 (3R,4S,5R)-methyl 3,4-dibenzyloxy-5-hydroxycyclohex-1-ene-1-carboxylate 
• 40983-58-2 methyl shikimate 
• 77-95-2 D-(-)-quinic acid 
• 50605-62-4 3,4,5-tri-O-acetyl quinate de methyle 
• 1147996-14-2 (1S,2S,3R,4S,5R)-methyl 2,3,4,5-tetraacetoxy-cyclohexanecarboxylate 
• 120586-27-8 menthyl (1S,2R,3S,4S)-5,6-dibenzyloxy-3-<(S)_S-2-pyridylsulphinyl>-7-oxabicyclo<2.2.1>hept-5-ene-2-carboxylate (endo) 
• 120586-28-9 menthyl (1S,2R,3S,4S)-5,6-dibenzyloxy-3-<2-pyridylthio>-7-oxabicyclo<2.2.1>hept-5-ene-2-carboxylate 
• 138-59-0 shikimic acid 
• 96290-95-8 dimethyl (2R,3R,4S,5R)-2-acetoxy-3,4,5-tris(benzyloxy)cyclohexane-1,1-dicarboxylate 
• 96290-94-7 dimethyl (2S,3R,4S,5R)-2-acetoxy-3,4,5-tris(benzyloxy)cyclohexane-1,1-dicarboxylate 

Downstream Products

• 40983-58-2 methyl shikimate 
• 352533-29-0 methyl (3S,4R,5R)-5-acetoxy-3-azido-4-hydroxycyclohex-1-ene-1-carboxylate 
• 352533-39-2 methyl (3R,4S,5R)-4-acetamido-5-acetoxy-3-aminocyclohex-1-ene-1-carboxylate 
• 352533-37-0 methyl (3R,4S,5R)-4-acetamido-5-acetoxy-3-azidocyclohex-1-ene-1-carboxylate 
• 352533-31-4 methyl (3S,4R,5R)-5-acetoxy-3-azido-4-(methanesulfonyloxy)cyclohex-1-ene-1-carboxylate 
• 352533-33-6 methyl (3S,4R,5R)-3-acetamido-5-acetoxy-4-(methanesulfonyloxy)cyclohex-1-ene-1-carboxylate 
• 143308-74-1 (3aR,7R,7aS)-methyl 7-acetoxy-2,2-dimethyl-3a,6,7,7atetrahydrobenzo[d][1,3]dioxole-5-carboxylate 
• 129253-74-3 methyl 3,4,5-tri-O-acetylshikimate 

Relevant articles and documents

Asymmetric syntheses of (-)-methyl shikimate and (-)-5a-carba-β-d-gulopyranose from d-arabinose via Mukaiyama-type intramolecular aldolization

New asymmetric syntheses of (-)-methyl shikimate 1 and (-)-5a-carba-β-d-gulopyranose 11 from d-arabinose through a common route which employed Mukaiyama-type intramolecular aldolization as a key step were described.

Synthese de derives des acides quinique et shikimique

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A NEW SYNTHETIC ROUTE TO METHYL (-)-SHIKIMATE BY ASYMMETRIC DIELS-ALDER REACTON OF (S)S-3-(2-PYRIDYLSULFINYL)ACRYLATE

A 7-oxabicycloheptene derivative (7a) that substituted effectively for the synthesis of (-)-shikimic acid was prepared by an asymmetric Diels-Alder reaction of (S)s-3-(2-pyridylsulfinyl)acrylate (2) with 3,4-dibenzyloxyfuran (4).The bicy