175550-09-1

Basic information

• Product Name: Acetic acid (2S,5R,6R)-5-hydroxy-6-phenylsulfanylethynyl-5,6-dihydro-2H-pyran-2-ylmethyl ester
• Synonyms: Acetic acid (2S,5R,6R)-5-hydroxy-6-phenylsulfanylethynyl-5,6-dihydro-2H-pyran-2-ylmethyl ester
• CAS NO: 175550-09-1
• Molecular Weight: 304.367
• Mol File: 175550-09-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Acetic acid (2S,5R,6R)-5-hydroxy-6-phenylsulfanylethynyl-5,6-dihydro-2H-pyran-2-ylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (2S,5R,6R)-5-hydroxy-6-phenylsulfanylethynyl-5,6-dihydro-2H-pyran-2-ylmethyl ester(175550-09-1)
• EPA Substance Registry System: Acetic acid (2S,5R,6R)-5-hydroxy-6-phenylsulfanylethynyl-5,6-dihydro-2H-pyran-2-ylmethyl ester(175550-09-1)

Safety Data

• Hazardous Substances Data: 175550-09-1(Hazardous Substances Data)

Upstream product

• 63139-23-1 phenylthioethynyl trimethylsilane 
• 3366-47-0 2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-arabinohex-1-enopyranose 

Downstream Products

• 167257-12-7 Acetic acid (2S,5R,6S)-5-(tert-butyl-diphenyl-silanyloxy)-6-phenylsulfanylethynyl-5,6-dihydro-2H-pyran-2-ylmethyl ester 
• 175673-11-7 Acetic acid (2S,5R,6S)-5-hydroxy-6-phenylsulfanylethynyl-5,6-dihydro-2H-pyran-2-ylmethyl ester 
• 175673-14-0 (2S,3R,6S)-2-((Z)-2-Benzenesulfonyl-2-triethylsilanyl-vinyl)-6-(tert-butyl-diphenyl-silanyloxymethyl)-3-trimethylsilanyloxy-3,6-dihydro-2H-pyran 
• 175673-13-9 (2S,3R,6S)-2-((Z)-2-Benzenesulfonyl-2-triethylsilanyl-vinyl)-6-(tert-butyl-diphenyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-ol 
• 175550-12-6 (2S,3R,6S)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-2-((Z)-2-phenylsulfanyl-2-triethylsilanyl-vinyl)-3,6-dihydro-2H-pyran-3-ol 
• 175673-12-8 Acetic acid (2S,5R,6S)-5-hydroxy-6-((Z)-2-phenylsulfanyl-2-triethylsilanyl-vinyl)-5,6-dihydro-2H-pyran-2-ylmethyl ester 
• 175550-11-5 (2S,3R,6S)-6-Hydroxymethyl-2-((Z)-2-phenylsulfanyl-2-triethylsilanyl-vinyl)-3,6-dihydro-2H-pyran-3-ol 
• 167107-99-5 Acetic acid (2S,5R,6R)-5-(tert-butyl-diphenyl-silanyloxy)-6-phenylsulfanylethynyl-5,6-dihydro-2H-pyran-2-ylmethyl ester 

Relevant articles and documents

C-Glycosidation with silylacetylenes to D-glucals

C-Glycosidation is of significance for introducing carbon chains to sugar nuclei from the chiral pool. Silylacetylenes have been shown to be sufficiently reactive for the selective introduction of acetylenic groups, usefull for organic synthesis.

Heteroconjugate Addition at C-1 Position of Pyranose Derivative, Pseudoenantiomeric Methodology for Asymmetric Introdution

A new synthetic method providing both enentiomers by heteroconjugate addition strategy is described for stereocontrolled synthesis of optically active compounds from sugar chirons.Preparation includes introduction of phenylthioacetylene, acidic epimerizat