17579-35-0Relevant articles and documents
Iron(III) picolinate-catalyzed oxidative demethylation of N,N- dimethylaniline with hydrogen peroxide in the presence of acetic anhydride
Kotani, Eiichi,Takeya, Tetsuya,Shimizu, Hideaki,Egawa, Hirotaka,Yamamoto, Takeshi,Tobinaga, Seisho
, p. 2089 - 2092 (1997)
Oxidation of N,N-dimethylaniline (1) utilizing the Fe(PA)3/H2O2/MeCN system and the Fe(ClO4)3-9H2O/PAH-Py/H2O2/MeCN system, simple model systems for mono-oxygenases, in the presence of acetic arthydride (Ac2O) afforded predominantly the N-acetylative demethylation product, N- methylacetanilide (4), along with a few other compounds.