17595-84-5

Basic information

• Product Name: Benzoic acid, 2-(2-thienyl)-, methyl ester
• CAS NO: 17595-84-5
• Molecular Formula: C12H10O2S
• Molecular Weight: 218.276
• Mol File: 17595-84-5.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-(2-thienyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-(2-thienyl)-, methyl ester(17595-84-5)
• EPA Substance Registry System: Benzoic acid, 2-(2-thienyl)-, methyl ester(17595-84-5)

Safety Data

• Hazardous Substances Data: 17595-84-5(Hazardous Substances Data)

Upstream product

• 188290-36-0 thiophene 
• 342-54-1 2-(methoxycarbonyl)benzenediazonium tetrafluoroborate 
• 134-20-3 2-carbomethoxyaniline 
• 67-56-1 methanol 
• 6072-49-7 2-(2'-carboxyphenyl)thiophene 
• 610-94-6 2-bromobenzoic acid methyl ester 
• 6165-68-0 thiophene boronic acid 
• 610-97-9 o-iodo-methyl-benzoic acid 
• 54663-78-4 tributyl(thien-2-yl)stannane 
• 17763-70-1 methyl 2-(trifluoromethylsulfonyloxy)benzoate 

Downstream Products

• 6072-49-7 2-(2'-carboxyphenyl)thiophene 
• 881690-46-6 4,4-di-p-tolyl-4H-indeno[1,2-b]thiophene 
• 773872-97-2 [2-(2-thienyl)phenyl]methanol 
• 5706-08-1 4H-Indeno<1,2-b>thiophen-4-one 
• 194416-92-7 o-(5-formyl-2-thienyl)benzonitrile 
• 97677-81-1 2-(2'-chloroformylphenyl)thiophene 
• 194416-98-3 2-[5-(2-Butyl-benzoimidazol-1-ylmethyl)-thiophen-2-yl]-benzoic acid methyl ester 
• 194417-03-3 2-(5-Benzotriazol-1-ylmethyl-thiophen-2-yl)-benzoic acid methyl ester 
• 194416-93-8 Methyl 2-(5'-hydroxymethylthien-2'-yl)benzoate 
• 194416-95-0 Methyl 2-(5'-chloromethyl-2'-thienyl)benzoate 
• 897446-34-3 N-(2-aminophenyl)-2-thiophen-2-ylbenzamide 
• 194416-91-6 Methyl 2-(5'-formylthien-2'-yl)benzoate 
• 78515-62-5 4H-Indeno<1,2-b>thiophen-4-one Triphenylphosphazine 

Relevant articles and documents

Palladium-catalyzed intramolecular aromatic C-H acylation of 2-arylbenzoyl fluorides

The catalytic intramolecular cyclization of acyl fluorides using a Pd(OAc)2/PCy3 system is described. A wide range of 2-arylbenzoyl fluoride derivatives can be used as fluorenone precursors and the reaction proceeds via an intramolecular coupling between aromatic C-H bonds with acyl C-F bonds. The reaction can be applied to the synthesis of indenofluorenedione derivatives and to the construction of other molecules with fivemembered rings.

Simple and Efficient Large-scale Metal-free Synthesis of o-(5-Formyl-2-thienyl)benzonitrile and o-(5-Formyl-2-furyl)benzonitrile

-

AgONO-Assisted Direct C-H Arylation of Heteroarenes with Anilines

A novel copper-catalyzed C-H arylation of heteroarenes with anilines by an in situ diazonium reaction is established by using silver nitrite (AgONO) as an unconventional nitrosating reagent under acid-free conditions. It provides a complementary approach for the C-H arylation of electron-rich heteroarenes with aromatic amines affording a variety of heterobiaryls in moderate to good yields.