176041-42-2

Basic information

• Product Name: Silane, tris(1-methylethyl)[(3-methyl-2-furanyl)oxy]-
• CAS NO: 176041-42-2
• Molecular Formula: C14H26O2Si
• Molecular Weight: 254.445
• Mol File: 176041-42-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Silane, tris(1-methylethyl)[(3-methyl-2-furanyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, tris(1-methylethyl)[(3-methyl-2-furanyl)oxy]-(176041-42-2)
• EPA Substance Registry System: Silane, tris(1-methylethyl)[(3-methyl-2-furanyl)oxy]-(176041-42-2)

Safety Data

• Hazardous Substances Data: 176041-42-2(Hazardous Substances Data)

Upstream product

• 22122-36-7 3-methyl-5H-furan-2-one 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Downstream Products

• 141054-54-8 rel-(S)-5-<(S)-1'-benzyloxycarbonyl-2'-pyrrolidinyl>-3-methylfuran-2(5H)-one 
• 141054-54-8 rel-(R)-5-<(S)-1'-benzyloxycarbonyl-2'-pyrrolidinyl>-3-methylfuran-2(5H)-one 
• 1089205-89-9 C₂₁H₃₁BrO₄Si 
• 1203511-19-6 C₂₁H₃₁BrO₄Si 
• 1326304-63-5 5-(4-fluorophenyl)-3-methylfuran-2(5H)-one 
• 71589-55-4 5-(4-methoxyphenyl)-3-methylfuran-2(5H)-one 
• 15121-75-2 3-methyl-5-phenylfuran-2-(5H)-one 

Relevant articles and documents

Comparative studies of palladium and copper-catalysed γ-arylation of silyloxy furans with diaryliodonium salts

The γ-arylation of substituted silyl-activated butenolides has been studied using a broad scope of unsymmetrical hypervalent diaryliodonium salts via a palladium- or copper-catalysed coupling reaction, yielding interesting reactivity trends. The mild catalytic conditions and coupling partner variability provide access to synthetically useful building blocks toward the pursuit of aryl-lactone containing natural products and allows for facile diversification.

Synthesis of Penta-2,4-dien-1-imines and 1,2-Dihydropyridines by Rhodium-Catalyzed Reaction of N-Sulfonyl-1,2,3-triazoles with 2-(Siloxy)furans

A rhodium(II)-catalyzed reaction of N-sulfonyl-1,2,3-triazoles with 2-(siloxy)furans is reported. Either open-chain penta-2,4-dien-1-imines or cyclic 1,2-dihydropyridines are selectively obtained depending on the ligand on rhodium(II).

Diastereoselective addition of nitro compounds to α,β- unsaturated γ-butyrolactones

Herein, we report our results on the diastereoselective addition of nitro compounds to α,β-unsaturated γ-butyrolactones, which afforded the corresponding Michael adducts 9-17 in moderate to good yields and good to excellent diastereoisomeric ratio. A one-pot conversion of α,β- unsaturated γ-butyrolactones 7 and 8 to the corresponding trisubstituted keto-γ-butyrolactones 24 and 25 via a tandem Michael-Nef protocol is also described.