176237-60-8

Basic information

• Product Name: 2,2-diethoxy-6-nitro-5-phenylhexan-3-one
• CAS NO: 176237-60-8
• Molecular Weight: 309.362
• Mol File: 176237-60-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2-diethoxy-6-nitro-5-phenylhexan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-diethoxy-6-nitro-5-phenylhexan-3-one(176237-60-8)
• EPA Substance Registry System: 2,2-diethoxy-6-nitro-5-phenylhexan-3-one(176237-60-8)

Safety Data

• Hazardous Substances Data: 176237-60-8(Hazardous Substances Data)

Upstream product

• 176237-56-2 3,3-diethoxy-2-morpholinobut-1-ene 
• 51933-13-2 3,3-Diethoxy-butan-2-one 

Relevant articles and documents

Mononitroalkylations of butane-2,3-dione

The morpholino enamine of monoprotected butane-2,3-dione reacts with cyclic and acyclic conjugated nitroalkenes in a Michael-type reaction to yield nitro-substituted α-diketones, after acidic hydrolysis of the mononitroalkylated enamine adducts. Cyclopentanone, hexahydro-1H-pentalen-2-one and octahydro-2H-inden-2-one derivatives are readily obtained by base-catalyzed intramolecular nitroaldol reaction of the acyclic hydrolysis products.