176650-93-4

Basic information

• Product Name: 3,5-BIS(3,5-DIMETHOXYBENZYLOXY)BENZYL BROMIDE
• Synonyms: 3,5-BIS(3,5-DIMETHOXYBENZYLOXY)BENZYL BROMIDE
• CAS NO: 176650-93-4
• Molecular Formula: C₂₅H₂₇BrO₆
• Molecular Weight: 503.38
• Product Categories: Building Blocks for Dendrimers;Functional Materials
• Mol File: 176650-93-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• Refractive Index: 1.58
• Storage Temp.: Refrigerator
• CAS DataBase Reference: 3,5-BIS(3,5-DIMETHOXYBENZYLOXY)BENZYL BROMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-BIS(3,5-DIMETHOXYBENZYLOXY)BENZYL BROMIDE(176650-93-4)
• EPA Substance Registry System: 3,5-BIS(3,5-DIMETHOXYBENZYLOXY)BENZYL BROMIDE(176650-93-4)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 176650-93-4(Hazardous Substances Data)

Usage

General Description

3,5-BIS(3,5-DIMETHOXYBENZYLOXY)BENZYL BROMIDE is a chemical compound that belongs to the family of benzyl bromides. It is characterized by the presence of two 3,5-dimethoxybenzyloxy groups attached to a benzyl bromide moiety. 3,5-BIS(3,5-DIMETHOXYBENZYLOXY)BENZYL BROMIDE is commonly used in organic synthesis and chemical reactions, particularly in the field of pharmaceutical research. It is often utilized as a reagent or intermediate in the preparation of various biologically active molecules, as well as in the production of synthetic compounds with potential pharmacological properties. 3,5-BIS(3,5-DIMETHOXYBENZYLOXY)BENZYL BROMIDE has garnered interest in the scientific community due to its versatile applications and potential contributions to drug discovery and development.

InChI:InChI=1/C25H27BrO6/c1-27-20-7-18(8-21(11-20)28-2)15-31-24-5-17(14-26)6-25(13-24)32-16-19-9-22(29-3)12-23(10-19)30-4/h5-13H,14-16H2,1-4H3

Upstream product

• 176650-92-3 3,5-bis(3,5-dimethoxybenzyloxy)benzyl alcohol 
• 705-76-0 3,5-dimethoxybenzyl alcohol 
• 877-88-3 3,5-dimethoxybenzyl bromide 

Downstream Products

• 464884-88-6 bis-{3,5-bis[3,5-(dimethoxy)benzyloxy]benzyl}-dimethylammonium bromide 
• 1191933-49-9 C₆₃H₆₂O₁₆ 
• 1353901-72-0 C₅₇H₅₈O₁₅ 

Relevant articles and documents

Dendritic [2]rotaxanes: Synthesis, characterization, and properties

A series of dendritic ammonium salts have been designed and synthesized. Subsequently, they were used to construct the corresponding [2]rotaxanes by a template-directed clipping approach. Unusually, two unsymmetrical dendritic [2]rotaxanes containing fluorophore (pyrene units) were also obtained; their optical properties, such as UV/vis absorption and fluorescence, were measured. The results indicate that these two rotaxanes possess stronger intermolecular interaction in the solid state than in solution. As a result, solutions of high concentration readily formed the excimer. These special rotaxanes might be applied in dynamic fluorescence-reponsive materials, and the rotaxane structure will also be used as a strategy to adjust the aggregated behaviors of fluorescent molecules.

Chromophore-labeled dendrons as light harvesting antennae

A novel series of polyether dendrimer segments (dendrons) end-capped with pyrenyl, naphthyl, or methyl groups has been prepared by a convergent growth method. Steady-state fluorescence measurements indicate the absence of intramolecular naphthalene excimer in the naphthyl-capped dendrons. However, in the pyrenyl-capped dendrons, excimer emission predominates. Fluorescence from both the naphthyl monomer and pyrenyl excimer are quenched when a suitable electron donor (e.g., a 3-[dimethylamino]phenoxy group) is covalently attached at the dendron focal point. No sensitized emission from the dendron backbone is observed in the chromophore-labeled dendrons, although the control methyl-capped dendron fluoresces weakly at 310 nm when excited at 284 nm. Absorption and fluorescence spectra, fluorescence quantum yields, and fluorescence lifetimes for the chromophore-labeled dendrons axe reported.