176848-41-2Relevant articles and documents
Enantioselective microbial oxidation of allyl alcohols
Matsumoto, Kazutsugu,Kawabata, Yoichi,Okada, Satoshi,Takahashi, Jun,Hashimoto, Key,Nagai, Yuto,Tatsuta, Junichi,Hatanaka, Minoru
, p. 1428 - 1429 (2007)
A new route to the optically active allyl alcohols by microbial oxidation is disclosed. Yamadazyma farinosa IFO 10896, a yeast, efficiently catalyzes the enantioselective oxidation of allyl alcohols to afford the corresponding optically active alcohols as the remaining substrates. This reaction is applicable to both cyclic and acyclic compounds. Copyright
Oxa-Michael addition promoted by the aqueous sodium carbonate
Guo, Shi-Huan,Xing, Sheng-Zhu,Mao, Shuai,Gao, Ya-Ru,Chen, Wen-Liang,Wang, Yong-Qiang
supporting information, p. 6718 - 6720 (2014/12/11)
An efficient Michael addition of alcohols to activated alkenes promoted by sodium carbonate with water as reaction medium has been developed. The reaction provides a general, economical and environmentally friendly approach for the synthesis of β-alkoxycarbonyl compounds.
Temperature-dependent isomerisation versus net fragmentation of secondary allylic alcohols with Grubbs' catalyst
Gurjar, Mukund K.,Yakambram, Pedduri
, p. 3633 - 3636 (2007/10/03)
Secondary allylic alcohols with 10 mol% of Grubbs catalyst in refluxing toluene/1,2-dichloroethane undergo isomerisation to ethyl ketones whereas with 100 mol% of Grubbs catalyst at room temperature, a net fragmentation reaction with the loss of a carbon atom occurs, to provide a methyl ketone. Probable mechanisms are described.
