177161-38-5

Basic information

• Product Name: [Zn(OCOC₆H₅)(C₅H₄NCH₂NHC₆H₄S)]
• CAS NO: 177161-38-5
• Molecular Weight: 401.804
• Mol File: 177161-38-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Zn(OCOC₆H₅)(C₅H₄NCH₂NHC₆H₄S)](CAS DataBase Reference)
• NIST Chemistry Reference: [Zn(OCOC₆H₅)(C₅H₄NCH₂NHC₆H₄S)](177161-38-5)
• EPA Substance Registry System: [Zn(OCOC₆H₅)(C₅H₄NCH₂NHC₆H₄S)](177161-38-5)

Safety Data

• Hazardous Substances Data: 177161-38-5(Hazardous Substances Data)

Upstream product

• 553-72-0 zinc benzoate 
• 52797-54-3 2-{[(pyridin-2-yl)methyl]amino}-benzenethiol 

Relevant articles and documents

Zinc complexes of the N,N,S ligand (mercaptophenyl)(picolyl)amine

The zinc complex chemistry of the tridentate thiol ligand N-(2-mercaptophenyl)(2-picolyl)amine (MPPAH) differs considerably from that of the aliphatic analogue N-(2-mercaptoethyl)(2-picolyl)amine reported previously. This is due to the lower basicity and hence bridging tendency of its aromatic thiolate function. With zinc salts of oxo anions the 1:1 complexes (MPPA)ZnX (1a-c: X = ONO2, OAc, OBz) are formed which according to spectroscopic data are monomeric while the halide (MPPA)ZnBr (2) seems to be polymeric. In the absence of coordinating anions the monomeric 2:1 complex (MPPA)2Zn (3) results which according to a crystal structure determination contains tetrahedral zinc coordinated by one MPPA ligand in a tridentate fashion while the other is only monodentate and sulfur-bound. A similar N2S2 coordination can be deduced for the 1:1:1 complex (MPPA)Zn(STrt) (4) resulting from ZnEt2, MPPAH and triphenylmethanethiol. VCH Verlagigesdlschaft mbH, 1996.