177263-77-3 Usage
Description
(2-(diphenylphosphino)phenyl)MethanaMine, with the chemical formula C19H16NP, is a phosphine ligand that plays a significant role in organometallic chemistry and catalysis. This chemical compound features a phosphine group and a benzene ring, which allows it to coordinate with transition metals in catalytic reactions. Its central role in various chemical reactions, such as the formation of carbon-carbon and carbon-heteroatom bonds, makes it a versatile component in the synthesis of pharmaceuticals, agrochemicals, and materials. Furthermore, its unique electronic and steric properties contribute to its value in the development of new and efficient catalysts.
Uses
Used in Pharmaceutical Synthesis:
(2-(diphenylphosphino)phenyl)MethanaMine is used as a ligand in the synthesis of pharmaceuticals for its ability to coordinate transition metals, facilitating the formation of carbon-carbon and carbon-heteroatom bonds that are crucial in creating complex molecular structures.
Used in Agrochemical Production:
In the agrochemical industry, (2-(diphenylphosphino)phenyl)MethanaMine is utilized as a ligand to assist in the development of new and efficient catalysts, which are essential for the synthesis of various agrochemical products.
Used in Material Science:
(2-(diphenylphosphino)phenyl)MethanaMine is employed as a component in the synthesis of advanced materials, where its unique electronic and steric properties contribute to the creation of materials with specific characteristics and applications.
Used in Catalyst Development:
(2-(diphenylphosphino)phenyl)MethanaMine is used as a key component in the development of new catalysts, thanks to its ability to coordinate with transition metals and its unique electronic and steric properties, which enhance the efficiency and effectiveness of catalytic processes.
Check Digit Verification of cas no
The CAS Registry Mumber 177263-77-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,7,2,6 and 3 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 177263-77:
(8*1)+(7*7)+(6*7)+(5*2)+(4*6)+(3*3)+(2*7)+(1*7)=163
163 % 10 = 3
So 177263-77-3 is a valid CAS Registry Number.
177263-77-3Relevant articles and documents
The preparation of trans-2,5- dialkylpyrrolidinylbenzyldiphenylphosphines: New phosphinamine ligands for asymmetric catalysis
Cahill, John P.,Bohnen, Frank M.,Goddard, Richard,Krueger, Carl,Guiry, Patrick J.
, p. 3831 - 3839 (1998)
The preparation of new phosphinamine ligands 3a, 3b, possessing an enantiopure trans-2,5-dialkylpyrrolidinyl unit is described. Of the three synthetic approaches investigated, two proved successful with similar overall yields of 50-60%. One approach forms
HYDROGENATION OF CARBONYLS WITH TETRADENTATE PNNP LIGAND RUTHENIUM COMPLEXES
-
, (2019/10/04)
The present invention relates to catalytic hydrogenation processes, using Ru complexes with tetradentate ligands of formula L in hydrogenation processes for the reduction of ketone, aldehyde, ester or lactone into the corresponding alcohol or diol respectively. The described processes use a ruthenium complex of the formula (1) as defined below, and where the ligand (L) is defined by the Markush formula shown above.
Direct asymmetric α-allylation of ketones with allylic alcohols Via Pd/enamine cooperative function
Yasuda, Shigeo,Kumagai, Naoya,Shibasaki, Masakatsu
, p. 745 - 757 (2013/08/15)
Direct asymmetric α-allylation of ketones with allylic alcohols is described. The combination of palladium with a new phosphine ligand bearing a chiral proline moiety promoted the reaction to afford the corresponding α-allylated ketones in moderate yield and enantioselectivity.
